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Routes to N-Heterocyclic Carbene Complexes
ChemInform, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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N-Heterocyclic Carbenes in Organocatalysis
2010The use of N-heterocyclic carbenes (NHCs) to promote organocatalytic transformations has rapidly expanded in recent years, building upon the classic use of these compounds to generate acyl anion equivalents from aldehydes. This chapter gives an overview of the recent progress made in this area, describing the use of NHCs to generate synthetic ...
Craig D. Campbell +2 more
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Organic Letters, 2017
Boron-hydrogen bond insertion reactions of N-heterocyclic carbene (NHC) boranes and diazoesters can be catalyzed by NHC-boryl iodides and produce stable α-NHC-boryl esters. The conditions of the reaction resemble the previous rhodium-catalyzed transformations (only the catalyst is different); however, the mechanisms of the two reactions are probably ...
Thomas H. Allen +4 more
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Boron-hydrogen bond insertion reactions of N-heterocyclic carbene (NHC) boranes and diazoesters can be catalyzed by NHC-boryl iodides and produce stable α-NHC-boryl esters. The conditions of the reaction resemble the previous rhodium-catalyzed transformations (only the catalyst is different); however, the mechanisms of the two reactions are probably ...
Thomas H. Allen +4 more
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Journal of the American Chemical Society, 2016
The synthesis of hydridosilylenes Ter(H)Si: 3a (Ter: 2,6-bis(2,4,6-trimethylphenyl)phenyl) and Ter*(H)Si: 3b (Ter*: 2,6-bis(2,4,6-triiso-propylphenyl)phenyl) stabilized by the N-heterocyclic carbene (NHC) ImMe4 is reported. The synthesis of stabilized hydridosilylenes 3 was accomplished by a previously unknown NHC-induced fragmentation of ...
Dennis, Lutters +3 more
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The synthesis of hydridosilylenes Ter(H)Si: 3a (Ter: 2,6-bis(2,4,6-trimethylphenyl)phenyl) and Ter*(H)Si: 3b (Ter*: 2,6-bis(2,4,6-triiso-propylphenyl)phenyl) stabilized by the N-heterocyclic carbene (NHC) ImMe4 is reported. The synthesis of stabilized hydridosilylenes 3 was accomplished by a previously unknown NHC-induced fragmentation of ...
Dennis, Lutters +3 more
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Organocatalysis by N-Heterocyclic Carbenes
Chemical Reviews, 2007Dieter, Enders +2 more
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The Beginnings of N‐Heterocyclic Carbenes
Angewandte Chemie International Edition, 2010openaire +2 more sources
Heterocyclic Carbenes: Synthesis and Coordination Chemistry
Angewandte Chemie - International Edition, 2008F Ekkehardt Hahn, Mareike C Jahnke
exaly
The Measure of All Rings—N‐Heterocyclic Carbenes
Angewandte Chemie - International Edition, 2010Frank Glorius
exaly
Palladium–(N‐Heterocyclic Carbene) Hydrogenation Catalysts
Angewandte Chemie, 2005Sprengers, J.W. +4 more
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