Molecules, 2009 Novel 1,3-dialkylperhydrobenzimidazolinium chloride salts were prepared as precursors of N-heterocyclic carbenes 3a-e by reacting N,N’-dialkylcyclohexandiamine, triethyl orthoformate and ammonium chloride.
Murat Yiğit
doaj +1 more source
Synthesis of Platinum(II) N-Heterocyclic Carbenes Based on Adenosine
Molecules, 2021 Organometallic derivatization of nucleosides is a highly promising strategy for the improvement of the therapeutic profile of nucleosides. Herein, a methodology for the synthesis of metalated adenosine with a deprotected ribose moiety is described ...
Maria Inês P. S. Leitão +3 more
doaj +1 more source
The double role of ionic liquids in organic electrosynthesis: Precursors of N-heterocyclic carbenes and green solvents. Henry reaction [PDF]
, 2009 N-heterocyclic carbenes, electrogenerated by cathodic reduction of imidazolium-based room temperature ionic liquids (RTILs), are stable bases able to catalyze the Henry reaction.
FEROCI, Marta +3 more
core +1 more source
N-Heterocyclic carbene/Brønsted acid cooperative catalysis as a powerful tool in organic synthesis
Beilstein Journal of Organic Chemistry, 2012 The interplay between metals and N-heterocyclic carbenes (NHCs) has provided a window of opportunities for the development of novel catalytic strategies within the past few years.
Rob De Vreese, Matthias D’hooghe
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Electrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces
Nature Communications, 2020 N-heterocyclic carbenes (NHCs) have been widely used for the formation of monolayers but self-assembly methods come with drawbacks such as need for dry environment or using specifically-synthesized precursors.
Einav Amit +11 more
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A simple access to transition metal cyclopropenylidene complexes [PDF]
, 2015 The authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the DOE (DE-FG02-13ER16370) for financial support.We report the first example of BAC–Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use ...
Slawin, Alexandra MZ +12 more
core +1 more source
Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes
Nature Communications, 2018 Axially chiral compounds are commonly found in nature. Here, the authors show the highly enantioselective construction of axially chiral biaryls via an N-heterocyclic carbenes-catalyzed [3+3] atroposelective annulation of ynals with cyclic 1,3-diones.
Changgui Zhao +5 more
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Direct Synthesis of N‐Heterocyclic Carbene‐Stabilized Copper Nanoparticles from an N‐Heterocyclic Carbene–Borane [PDF]
Chemistry – A European Journal, 2019 AbstractN‐Heterocyclic carbene (NHC)‐stabilized copper nanoparticles (NPs) were synthesized from an NHC–borane adduct and mesitylcopper(I) under thermal conditions (refluxing toluene for 2.5 h). NPs with a size distribution of 11.6±1.8 nm were obtained. The interaction between Cu NPs and NHC ligands was probed by X‐ray photoelectron spectroscopy, which
Frogneux, Xavier +9 more
openaire +3 more sources
Rate and equilibrium constants for the addition of N-heterocyclic carbenes into benzaldehydes : a remarkable 2-substituent effect [PDF]
, 2015 We thank the Royal Society for a University Research Fellowship (ADS), the EPSRC (CJC and RM) grant number EP/G013268/1 and the European Research Council under the European Union's Seventh Framework Programme (FP7/2007-2013) ERC grant agreement no 279850
Collett, Christopher John +17 more
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Sydnone Methides—A Forgotten Class of Mesoionic Compounds for the Generation of Anionic N‐Heterocyclic Carbenes [PDF]
, 2021 Sydnone methides are described from which only one single example has been mentioned in the literature so far. Their deprotonation gave anions which can be formulated as π-electron rich anionic N-heterocyclic carbenes.
Andreas Schmidt +11 more
core +3 more sources