Results 91 to 100 of about 6,045 (246)

Potential contribution of biomass gasification‐based technology in energy transition: a technical review coupled with bibliometric studies

open access: yesBiofuels, Bioproducts and Biorefining, EarlyView.
Abstract Biomass gasification technology has been extensively researched around the world; however, there is a need to evaluate the current research landscape and evolutionary direction of research in the broader context of energy transition. A systematic bibliometric analysis of the Web of Science database was performed for articles that fall within ...
Olasunkanmi Opeoluwa Adeoye   +5 more
wiley   +1 more source

Unlocking Enhanced Hydrogen Storage in Naphthalene via K‐Induced Acidity and Metal Dispersion in Dendritic Catalysts

open access: yesCarbon and Hydrogen, EarlyView.
Dendritic micro‐mesoporous composite catalysts through K‐induced enhancement of acidity and metal dispersion were developed. ABSTRACT Novel dendritic ZSM‐22/DMSNs (ZD) micro‐mesoporous composites with center–radial pore structure and suitable acidity were developed by nano‐assembly strategy. Subsequently, Pt/ZD‐K catalysts were synthesized based on the
Dongze Li   +9 more
wiley   +1 more source

Recent Strategies Toward Durable and Ion‐Tolerant Transition Metal‐Based Electrocatalysts in Seawater Electrolysis

open access: yesCarbon Energy, EarlyView.
Recent strategies address these challenges through ion‐specific regulation, encompassing chloride‐tolerant and chloride‐regulating anodes together with cathode designs that suppress OH− accumulation and Mg2+/Ca2+ coupling. This ion‐management‐oriented framework provides general guidelines for achieving stable, selective, and scalable seawater ...
Lina Li   +5 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Photoinduced Electron Transfer (PET) as Key to Accelerate the Cycloreversion Reaction of Arylquadricyclanes

open access: yesChemistry – A European Journal, EarlyView.
It is demonstrated that the photoinduced cycloreversion of a methoxynaphthylquadricyclane in the presence of suitable photocatalysts gives quantitatively the corresponding norbornadiene. As this photochromic norbornadiene‐quadricyclane cycle has favorable properties for light energy conversion, this method provides a useful tool for the targeted ...
Julian Felix Maria Hebborn   +4 more
wiley   +1 more source

Enhancing Stability of Metallic Magnesium Nanoparticles toward Oxidation in Water via PEG‐Phosphonate Passivation

open access: yesChemistry – A European Journal, EarlyView.
Metallic magnesium nanoparticles are stabilized against rapid oxidation in water through surface passivation with phosphonic acid–terminated poly(ethylene glycol). By controlling the timing of ligand addition during synthesis, nanoparticle growth, morphology, and aqueous lifetime are tuned, extending stability from minutes to hours while preserving ...
Anupong Nuekaew   +2 more
wiley   +1 more source

Mild N‑Arylation of Sulfoximines With (Hetero)aryl Chlorides Enabled by α‐Methylnaphthyl‐tBuBrettPhos Palladium Triflate

open access: yesChemistry – A European Journal, EarlyView.
A readily accessible, air‐ and moisture‐stable palladium precatalyst, [Pd(1‐MeNAP)(tBuBrettPhos)]OTf, enables the direct N‐arylation of NH‐sulfoximines with (hetero)aryl chlorides under exceptionally mild conditions ideal for late‐stage diversification of drug‐like scaffolds.
Sourav Manna   +5 more
wiley   +1 more source

Click Capture SELEX for the Identification of Click‐Modified Aptamers Targeting Small Molecules in Solution

open access: yesChemistry – A European Journal, EarlyView.
Using kanamycin A as a model target, we developed click‐capture SELEX to identify nucleobase‐modified aptamers capable of binding small molecules in solution. This approach enables flexible incorporation of nucleobase modifications via CuAAC, allowing the chemical properties of the aptamer to be tailored to the target molecule.
Philipp Menke   +5 more
wiley   +1 more source

A High Energy Barrier DyIII2 Single‐Molecule Magnet Supported by a Bulky, Anionic N–O Bridging Ligand

open access: yesChemistry – A European Journal, EarlyView.
Complex [Dy2(hynad)2(dbm)4] was prepared by the employment of the anionic N–O‐based bridging and chelating N‐hydroxy‐1,8‐naphthalimide ligand, featuring a {Dy2(µ‐OR)2}4+ core and exhibiting zero‐field SMM behavior with a Ueff value of 171 K and double‐S‐shaped hysteresis loops, open up to 3.5 K.
Alexandros S. Armenis   +6 more
wiley   +1 more source

Prism[5]MaxQ: A Sulfated Prism[5]Arene and Its Molecular Recognition Properties Toward a Panel of Quaternary Ammonium Guests

open access: yesChemistry – A European Journal, EarlyView.
We report the synthesis and characterization of a sulfated prism[5]arene host (Prism[5]MaxQ). Prism[5]MaxQ displays ultrahigh binding affinity (Ka up to 1012 M−1) toward hydrophobic (di)cations in phosphate‐buffered saline (PBS). The work positions Prism[5]MaxQ as a new member of the family of ultrahigh‐affinity hosts poised for use as a sequestrant in
Emmanuel A. Bazan‐Bergamino   +1 more
wiley   +1 more source

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