Results 101 to 110 of about 6,045 (246)
Acid‐Catalyzed Rearrangement Reaction for Single‐Molecule Junction Formation
Chemistry – A European Journal, EarlyView.Hydrazobenzenes cannot form single‐molecule devices with gold electrodes in a nonpolar solvent, but with the addition of trifluoroacetic acid, robust single‐molecule junctions are created. Hydrazobenzenes likely undergo rearrangement reactions to form benzidines, which are then attached to gold contacts by dative NH2→Au interactions for junction ...
Yihao Zhang +3 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.We report a catalyst‐ and solvent‐free thermal condensation route to oligosilsesquioxanes from arylsilanetriols and disiloxanetetraols. Phenyl and 1‐naphthyl systems form ladder‐like structures, while 2‐naphthyl systems yields layered architectures.
Jan‐Falk Kannengießer +4 more
wiley +1 more source
A Diazo-free Equivalent of the Unsubstituted Carbyne Cation: Straightforward Synthesis of Naphthalenes and Pyridines via [12/13CH]+ Insertion. [PDF]
J Am Chem SocWenzel NS +8 more
europepmc +1 more source
Non‐negative Gaussian estimation of variance components in random effects models
Canadian Journal of Statistics, EarlyView.Abstract When used to estimate variance components (VCs), confidence intervals (CIs) can be truncated at zero, have a point estimate not in the quoted CI, be empty with positive probability, or be all‐inclusive. This is because they have conflicting dual roles, since they are considered to cover the parameter with a specified probability while also ...
André Plante, Michael Plante
wiley +1 more source
Generation of Mono- and Bisazabicyclic <i>o</i>-Quinodimethanes through Polarity-Matched and -Mismatched 6π-Azaelectrocyclization: Access to Substituted Naphthalenes. [PDF]
Org LettLee DJ, Shankar M, Acharya A, Giri R.
europepmc +1 more source
ChemPhysChem, Volume 26, Issue 6, March 15, 2025.The ionization of anthracene, acridine, and phenazine has been explored, along with the removal of one and two hydrogen atoms, to provide valuable information for astrochemists and to understand the behavior of the resulting structures and their electronic reorganization. Abstract In this study, we systematically explored the stability and isomerism of
Khaldia Zghida +3 more
wiley +1 more source
A Fast and Highly Stable Aqueous Calcium‐Ion Battery for Sustainable Energy Storage
ChemSusChem, Volume 18, Issue 6, March 15, 2025.Aqueous batteries provide a low‐cost, safer alternative to lithium‐ion batteries, but their viability is often limited by rapid electrode degradation. This study shows that replacing K+ with divalent Ca2+ ions in the electrolyte significantly boosts the stability of both copper hexacyanoferrate cathodes and polyimide anodes, enabling fast‐charging ...
Raphael L. Streng +4 more
wiley +1 more source
ChemSusChem, Volume 18, Issue 6, March 15, 2025.we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
wiley +1 more source
Divergent Synthesis of 1-Aminonaphthalene Derivatives via the Diels-Alder Reaction of 3-Aminoarynes. [PDF]
J Org ChemOkada T, Kawada M, Yoshida S.
europepmc +1 more source