Results 131 to 140 of about 525,806 (272)

Interplay of Bridge Topology and Conformation in Phenylene‐Bridged Trityl Diradicals

open access: yesChemistry – A European Journal, EarlyView.
We present a meta‐phenylene‐bridged trityl diradical that exhibits an unexpectedly weak antiferromagnetic exchange coupling J with a strong environment‐dependent magnitude. Combined VSM, EPR, DFT, and MD studies reveal that structural flexibility modulates σ‐, π‐, and through‐space exchange contributions, highlighting the crucial role of geometry in ...
Kevin Lars Kopp   +4 more
wiley   +1 more source

Narrow-linewidth erbium-doped fibre lasers

open access: yes, 1991
This thesis describes research towards narrow-linewidth and single-longitudinal-mode erbium-doped fibre lasers operating on the 1.55µm region. The work is concerned with the physics and technology of narrow-linewidth fibre lasers.
Cowle, Gregory John
core  

Heterovalent, Homometallic Rings: Synthesis, Optical, and EPR Studies of {TiIV7TiIII} Complexes

open access: yesChemistry – A European Journal, EarlyView.
A new class of heterovalent, homometallic complexes is reported, based on cyclic {TiIV7TiIII} cores with oxide and carboxylate bridges between nearest neighbors. The clusters show Class II mixed‐valent behavior at room temperature, but are valence localized at low temperature.
Selena J. Lockyer   +8 more
wiley   +1 more source

Synthesis, Physicochemical Characteristics, Self‐Assembly and Encapsulation Ability of per‐Ethylene‐Glycol‐Functionalized Resorcin[4]Arenes and Their Molecular Capsules: On the Road to Liquid Capsules

open access: yesChemistry – A European Journal, EarlyView.
Per‐ethylene‐glycol (EG)‐functionalized resorcin[4]arenes containing 12, 16, and 20 EG groups namely compounds 1d, 1e, and 1f, respectively, were prepared and found to self‐assemble, in organic solvents, into hexameric capsules. These capsules are more dynamic than the ones prepared based on alkyl substituted resorcin[4]arenes.
Gangadhara Angajala   +3 more
wiley   +1 more source

Europium Doped Atomically Precise Bismuth Oxido Nanoclusters as Molecular Building Blocks for Photoluminescent Hybrid Materials

open access: yesChemistry – A European Journal, EarlyView.
Europium doping of bismuth oxido nanoclusters (BiO‐NCs) provides stable hosts for Eu3+ in an asymmetric coordination environment, which in turn results in an intense 5D0→7F0 transition and long luminescence lifetimes. Transparent hybrid materials showing characteristic red photoluminescence are accessible via radical copolymerisation of these soluble ...
Rico Thomas   +5 more
wiley   +1 more source

Spectral, Semi‐Spectral, and Bandwidth Flow Cytometric Implementation of Multiplex Cytokine Bead Assays

open access: yesCytometry Part A, EarlyView.
ABSTRACT Multiplex cytokine bead assays (MCBA) have previously been carried out on conventional (aka classical, or bandwidth) flow cytometers, and issues involving unmixing distortions were encountered when using the manufacturer's set‐up beads for unmixing full‐spectrum data.
Jacob Laster   +3 more
wiley   +1 more source

Simulation‐Driven Optimization of a Borosilicate/Al/Al2O3/Graphene Multilayer SPR Sensor for Aqueous Detection of Metal Ions and Their Binary Mixtures

open access: yesElectron, EarlyView.
A cost‐effective surface plasmon resonance sensor using a borosilicate prism, 60 nm aluminum, an optimized 8–10 nm Al2O3 spacer, and graphene oxide achieves up to 338(°)/RIU sensitivity with narrow linewidth, enabling reliable detection and discrimination of Hg(II), Pb(II), Zn(II), and their binary mixtures in water.
Talia Tene   +4 more
wiley   +1 more source

Interface Engineering in Piezoelectric‐on‐Insulator Platforms: Coupling of Electrons, Photons, and Phonons for Multifunctional Integration

open access: yesElectron, EarlyView.
The underlying interface physics and engineering strategies across key POI material systems, including LiNbO3/Si, LiNbO3/SiC, LiNbO3/diamond, and AlN/diamond, were reviewed. The key engineering strategies such as atomic‐scale bonding optimization, nanostructuring, ultrathin phonon‐bridge interlayers, and ferroelectric domain wall engineering for ...
Yunjia Bao   +6 more
wiley   +1 more source

Fluorene‐based blue emitters: On the path to electrically pumped organic lasers

open access: yesFlexMat, EarlyView.
Electrically pumped efficient operation remains unrealized, a major challenge in optoelectronics. Fluorene‐based blue‐emitting semiconductors are promising gain media, thanks to their structural tunability and favorable emission properties. This review summarizes recent advances, highlights their reliability and versatility in lasing, and outlines key ...
Yong Yan   +7 more
wiley   +1 more source

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