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Crystal and molecular structures of the nido-carborane anions, 7,9- and 2,9-C2B9H12−
Journal of the Chemical Society, Dalton Transactions, 2002Deboronation of meta-carborane, closo-1,7-C2B10H12, with refluxing piperidine results in the quantitative formation of [(C5H10NH)2H+](nido-7,9-C2B9H12−) whose structure was determined by X-ray diffraction. Heating under vacuum liberates piperidine to give (C5H10NH2+)(nido-7,9-C2B9H12−).
Fox, M. A. +3 more
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Synthesis and vesicle formation of a nido-carborane cluster lipid for boron neutron capture therapy
Chem. Commun., 2004The nido-carborane lipid, which has a double-tailed moiety, was synthesized from heptadecanol in 5 steps. Analysis in a transmission electron microscope by negative staining with uranyl acetate showed that the lipid formed a stable vesicle in which calcein was encapsulated.
H Nakamura +4 more
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Photoinduced Selective B–H Activation of nido-Carboranes
Journal of the American Chemical SocietyThe development of new synthetic methods for B-H bond activation has been an important research area in boron cluster chemistry, which may provide opportunities to broaden the application scope of boron clusters. Herein, we present a new reaction strategy for the direct site-selective B-H functionalization of nido-carboranes initiated by photoinduced ...
Shengwen Xu +9 more
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Synthesis of new nido-carborane-containing 6-thiopurine derivatives
Russian Chemical Bulletin, 2023A. A. Telegina +3 more
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New nido-carborane-containing conjugates of purine: synthesis and antiviral activity
Russian Chemical Bulletin, 2022D. A. Gruzdev +7 more
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New aspects of acid-assisted nucleophilic substitution reactions of 11-vertex nido-carboranes
Polyhedron, 2022Mikhail M. Vinogradov +2 more
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NITRILIUM DERIVATES OF NIDO-CARBORANE IN SYNTHESIS OF TRANSITIONAL METAL COMPLEXES
This work was supported by Russian Science Foundation, project № 21-73-10199.Bogdanova, E. V. +3 more
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