Results 121 to 130 of about 62,179 (283)
Dynamic dielectric properties and the γ transition of bromine doped polyacrylonitrile
eXPRESS Polymer Letters, 2007 Based on monitoring the γ process (the lowest temperature-relaxation) in polyacrylonitrile (PAN) by dynamic dielectric spectroscopy, new evidence for the formation of a charge transfer complex between bromine dopants and nitrile groups is presented.
doaj +1 more source
Electrocatalytic C─C Bond Formation Via Cyanide Interception of CO2 Reduction Intermediates
Advanced Science, EarlyView.ABSTRACT Electrochemical CO2 reduction offers a sustainable route to convert greenhouse gas into high‐value‐added chemicals, yet product distributions remain largely limited to simple C1‐C3 molecules. Here, we report a new reaction in which CO2 reduction intermediates undergo direct C‐C coupling with an external carbon nucleophile under electrochemical
Gongbo Liu +10 more
wiley +1 more source
, 2016 In the mononuclear title complex, [CuI(C2H3N)(C26H24N2)], the Cu(I) ion has a distorted tetra-hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri-methyl-phen-yl)imino]-pyridine ligand, one N atom of ...
Nada Al-Najjar (7706888) +2 more
core +1 more source
Conversion of Alcohols into Amides Using Alumina-Methanesulfonic Acid (AMA) in Nitrile Solvents [PDF]
Iranian Journal of Chemistry & Chemical Engineering, 1999 The reaction of tertiary, secondary and benzylic alcohols with different nitriles in the presence of alumina-methanesulfonic acid (AMA) as a new reagent affords the corresponding amides in good yields (Table 1, 2).
Hashem Sharghi, Khodabakhsh Niknam
doaj
Preconditioning with subneurotoxic allyl nitrile: Protection against allyl nitrile neurotoxicity
High-dose cruciferous allyl nitrile can induce behavioral abnormalities in rodents, while repeated exposure to allyl nitrile at subneurotoxic levels can increase phase 2 detoxification enzymes in many tissues, although the brain has not been investigated
Tanii, Hideji +2 more
core
Advanced Science, EarlyView.Chemistry‐informed deep learning (DL) models based on the solvatochromic subgroup contribution (SSC) framework predict and interpret solvent‐dependent spectral shifts, revealing physically meaningful subgroup‐solvent interactions. ABSTRACT Solvent effects critically influence the photophysical and optical properties of molecules in solution, yet a ...
Jinyong Park +4 more
wiley +1 more source
Quantum‐Trained AI Enables Inverse Design of Organic Frontier Orbitals at Billion‐Scale
Advanced Science, EarlyView.Quantum‐trained AI links molecular substructures to frontier‐orbital energetics and enables interpretable screening across nearly one billion GDB‐13 molecules. By combining fragment‐ and ring‐level insights with donor–acceptor energy alignment against ITIC, the framework narrows an immense chemical space to a small set of promising candidates and ...
Yeongnam Ko, Se Jin Kim, Ki Chul Kim
wiley +1 more source
Flanking‐Group Engineering Unlocks Emerging Functionalities in Diketopyrrolopyrrole Semiconductors
Advanced ScienceDiketopyrrolopyrrole (DPP) is a cornerstone building block in high‐performance organic semiconductors, valued for its strong π‐conjugation, chemical robustness, and tunable optoelectronic characteristics.
Xiaoyun Wu +5 more
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Advanced Science, EarlyView.TNFRSF19 is an epigenetically silenced regulator of mitophagy in triple‐negative breast cancer. TNFRSF19 deficiency activates the TGFBR1–SMAD3–PINK1 axis to promote mitophagy and confer doxorubicin resistance, whereas decitabine‐mediated restoration of TNFRSF19 suppresses mitophagy and enhances doxorubicin sensitivity, revealing a targetable epigenetic–
Shiyang Liu +7 more
wiley +1 more source
Nitrile Rubbers and Vinyl Polymer Mixtures
, 1962 The outstanding resistance to abrasion, oil, fire and ozone of vulcanized nitrile rubber/PVC blends has stimulated cable manufacturers throughout the world.
C. Y. Almond
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