Results 81 to 90 of about 120,862 (337)

Interactive effects of genotype and N/S-supply on glucosinolates and glucosinolate breakdown products in Chinese cabbage (Brassica rapa L. ssp. pekinensis)

open access: yesJournal of Applied Botany and Food Quality, 2016
Chinese cabbage is rich in glucosinolates (GLS) and their breakdown products, mainly isothiocyanates (ITC), which are assumed to be human health-promoting compounds.
Christoph-Martin Geilfus   +4 more
doaj   +1 more source

A Comparative Life Cycle Assessment between a Metered Dose Inhaler and Electric Nebulizer [PDF]

open access: yes, 2017
Life cycle assessment (LCA) evaluates the environmental impact of a product based on the materials and processes used to manufacture the item as well as the item’s use and disposal.
Goulet, Brandon   +2 more
core   +3 more sources

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

open access: yesAdvanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje   +7 more
wiley   +1 more source

Homoallylic amines by reductive inter- and intramolecular coupling of allenes and nitriles

open access: yesBeilstein Journal of Organic Chemistry, 2011
The one-pot hydrozirconation of allenes and nitriles followed by an in situ transmetalation of the allylzirconocene with dimethylzinc or zinc chloride provides functionalized homoallylic amines.
Peter Wipf, Marija D. Manojlovic
doaj   +1 more source

Crystal structures of 2,6-dibromo-4-methylbenzonitrile and 2,6-dibromo-4-methylphenyl isocyanide

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2017
In the title crystals, C8H5Br2N, which are isomorphous, the steric bulk of the methyl group causes neighboring molecules to become mutually inclined. This prevents the formation of planar or nearly planar sheets, which were observed in the trichloro and ...
Wayland E. Noland   +4 more
doaj   +1 more source

Influence of pH and type of myrosinase complex on the products obtained in the myrosinase catalysed hydrolysis of glucosinolates – a MECC study [PDF]

open access: yes, 2007
Environmental conditions, e.g. pH and the presence of Fe2+ are well known factors that influence the product profile of the myrosinase catalysed hydrolysis of glucosinolates.
Bellostas, Natalia   +2 more
core  

Water Permeates and Plasticizes Amorphous Carbon Dots: Unraveling the Inner Accessibility of the Nanoparticles by Glass Transition Studies

open access: yesAdvanced Materials, EarlyView.
The water permeability of amorphous carbon dots (CDs) is demonstrated by investigating their plasticization. Novel polyamide‐based and amorphous nanoparticles are synthesized by controlling their inner packing density. Water plasticization is evidenced by the decrease of the CDs glass transition temperature with increasing the hydration degree.
Elisa Sturabotti   +8 more
wiley   +1 more source

Nitrogen Incorporation in CH_4-N_2 Photochemical Aerosol Produced by Far Ultraviolet Irradiation [PDF]

open access: yes, 2012
Nitrile incorporation into Titan aerosol accompanying hydrocarbon chemistry is thought to be driven by extreme UV wavelengths (λ120 nm is presently unaccounted for in atmospheric photochemical models.
Jimenez, Jose L.   +4 more
core  

Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers

open access: yesAdvanced Materials, EarlyView.
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez   +9 more
wiley   +1 more source

"Hydrogenated nitrile rubber with different hydrogenation degrees prepared by solution hydrogenation method"

open access: yesHecheng xiangjiao gongye
Hydrogenated nitrile rubber with hydrogenation degree of 90%, 95% and 99% was prepared by solution hydrogenation of nitrile rubber with ruthenium catalyst, the effects of catalyst amount, solid rubber content and filling volume of reactor on ...
LI Wen-xina, LIU Ping-pingb, LI Lina, WANG Huia
doaj   +1 more source

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