Synthesis of Chiral Isoxazoline Derivatives by Highly Diastereoface-Selective 1,3-Dipolar Cycloaddition of Nitrile Oxides Mediated by Magnesium Bromide and Ytterbium Trifluoromethanesulfonate [PDF]
, 2003 Hidetoshi Yamamoto +4 more
openalex +1 more source
Aggregate, EarlyView.The graphical abstract highlights the key concepts of this review, including chiral transfer and amplification mechanisms, macrocyclic compounds, circularly polarized luminescence (CPL) applications, chiral sensing, asymmetric catalysis, and stimuli‐responsive applications.
Wei Zhang, Mao‐Qin Liu, Yang Luo
wiley +1 more source
Leveraging Noncovalent Interactions for the Binding of CO by a Weakly Lewis Acidic Borane
Angewandte Chemie, EarlyView.We report a carbonyl complex featuring a simple tri‐coordinate borane, characterized by a Lewis acidity which is only marginally higher than B(NMe2)3. Exposure of {(Ph2P)xanth}3B to carbon monoxide under mild conditions (1 bar, 25 °C) reversibly yields {(Ph2P)xanth}3B·CO.
Agamemnon E. Crumpton +2 more
wiley +2 more sources
A Surface Hydrothermal Source of Nitriles and Isonitriles [PDF]
arXivGiant impacts can generate transient hydrogen-rich atmospheres, reducing atmospheric carbon. The reduced carbon will form hazes that rain out onto the surface and can become incorporated into the crust. Once heated, a large fraction of the carbon would be converted into graphite.
arxiv
Electrochemical characterization of systems for secondary battery application Second quarterly report, Aug. - Oct. 1966 [PDF]
Multisweep cyclic voltammetry for electrochemical characterization of systems for secondary battery ...
Gupta, N. K. +3 more
core +1 more source
Supramolecular Gels as Active Tools for Reaction Engineering
Angewandte Chemie, EarlyView.The unique combination of environments within gels, self‐assembled from low‐molecular‐weight gelators, offers the ability to control reactivity in new ways, achieving unique reaction outcomes, leading to the emerging concept of supramolecular gels as nanoreactors. Smart chemical engineering methods enable the use of such gels to fabricate materials and
David K. Smith
wiley +2 more sources
Silicon containing electroconductive polymers and structures made therefrom [PDF]
, 1991 An electropolymerized film comprised of polymers and copolymers of a monomer is formed on the surface of an anode. The finished structures have superior electrical and mechanical properties for use in applications such as electrostatic dissipation and ...
Distefano, Salvador +2 more
core +1 more source
Influence of the Solvent on the stereoselectivity of 1,3-Dipolar cycloaddition of Nitrile Oxides on Several 4-Substituted 2-Cyclopentenones [PDF]
, 2003 G. ADEMBRI +2 more
openalex +1 more source
Angewandte Chemie, EarlyView.By employing complex arylthianthrenium salts and readily available (hetero)aryl (pseudo)halides as starting materials, in conjunction with hypoboric acid as a reductant, structurally diverse (hetero)biaryl motifs can be rapidly synthesized via palladium‐catalyzed cross‐coupling reaction.
Yuanhao Xie, Li Zhang, Tobias Ritter
wiley +2 more sources
Synthesis of trifluoromethylated isoxazoles and their elaboration through inter- and intra-molecular C-H arylation [PDF]
, 2016 We report conditions for the preparation of a range of trifluoromethylated isoxazole building blocks through the cycloaddition reaction of trifluoromethyl nitrile oxide.
Blakemore, DC +6 more
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