Results 161 to 170 of about 14,073 (324)

Stabilizing the Hexacyanotrimethylenecyclopropane Electron Acceptor—Structural and Photophysical Characterization

Angewandte Chemie International Edition, EarlyView.
An improved low‐temperature synthesis enables the first comprehensive structural and spectroscopic characterisation of neutral hexacyanotrimethylenecyclopropane (CN6CP). Combined IR/Raman, UV–Vis and ssNMR analyses reveal a deeper understanding of its oxidation‐state‐dependent charge redistribution, σ‐aromaticity of the cyclopropane core, and redox ...
Jan P. Soyka, Alok Mahata, Anja Wiesner, Jennifer Hartfiel, Christian E. Halbig, Katharina J. Franke, Ute Resch‐Genger, Biprajit Sarkar, Siegfried Eigler   +8 more
wiley   +1 more source

Studies on the silicon chemistry of nitrile oxides

, 1984
The synthesis of silyl enol ethers from alkenyltrialkylstannanes, the synthesis of 0-(trimethylsilyl)hydroxamoyl chlorides and their utility as nitrile oxide precursors, and the addition of various silanes to acetonitrile oxide were studied ...
Bedell, Louis John
core  

A Convenient Method of Generation of Nitrile Oxides by Iodosylbenzene and Its Reaction.

, 2002
Seiji Tanaka, Miki Ito, Keiki Kishikawa, Shigeo Kohmoto, Makoto Yamamoto   +4 more
openalex   +2 more sources

Selective Oxidation of Amines to Imines or Nitriles by Manganese Dioxide in Air [PDF]

, 2014
Yo Han Kim, Seung Kyu Hwang, Yoon Sik Lee, Jung Won Kim   +3 more
openalex   +1 more source

Geminal Difunctionalization of Ketones via C─S Bond Insertion of Photogenerated Donor–Donor Diazo Compounds

Angewandte Chemie International Edition, EarlyView.
Geminal difunctionalization of readily available building blocks provides rapid access to molecular complexity. This work introduces a strategy for installing two distinct functional groups on a carbonyl carbon by transforming it into a donor–donor diazo compound, enabling both batch and flow applications with broad solvent compatibility.
Vincent George, Aryaman Pattanaik, Daniel Maddox, Lukas M. Sigmund, Giovanna Mejia, Sara Pahlén, Simon O. Angerer, Maria Schmoll, Lisa Marie Schneider, Nidhal Selmi, Mikhail Kabeshov, Giulia Bergonzini, Julia Rehbein, Burkhard König   +13 more
wiley   +1 more source

Biocatalytic Synthesis of Isoxazolines Enabled by Cryptic Nitrile Oxide Formation by a Vanadium-Dependent Chloroperoxidase. [PDF]

Angew Chem Int Ed Engl
Sharma M, Biegasiewicz KF.
europepmc   +1 more source

Stereo- and Regioselectivity in Nitrile Oxide Cycloaddition Reactions to Norethisterone Acetate as Dipolarophile

Paolo Quadrelli, Giuseppe Faita, Mariella Mella   +2 more
openalex   +1 more source

Preparation and reactivity of some stable nitrile oxides and nitrones

, 2000
Paul W. Groundwater, Miklós Nyerges, Imre Fejes, David E. Hibbs, David Bendell, Rosaleen J. Anderson, Alexander McKillop, Toqir Sharif, Weimin Zhang   +8 more
openalex   +1 more source

Forcing the Side‐on π‐Coordination of a C≡C Triple Bond to Technetium Using the As,CC,As Alkyne Pincer Ligand 1,2‐Bis(2‐(diisopropylarsaneyl)‐4‐(trifluoromethyl)phenyl)Ethyne

Angewandte Chemie International Edition, EarlyView.
Technetium alkyne complexes have eluded isolation for decades with the only indicators for their existence being the isolation of vinylidene carbenes or their follow‐up reaction products despite plentiful of reports for neighboring elements. Stable, crystalline Tc(III) and Tc(V) alkyne complexes (and their Re analogs) have now been prepared and fully ...
Maximilian Roca Jungfer, Moritz Johannes Ernst, Lukas Eberle, Marius Kesselring, Guilhem Claude, Joachim Ballmann   +5 more
wiley   +1 more source

Impact Modified Polyvinyl Chloride Based Thermoplastic Elastomers: Effect of Nitrile Butadiene Rubber and Graphene Oxide Loading

, 2021
K. Vijayan, Mathialagan Muniyadi, Yamuna Munusamy   +2 more
openalex   +1 more source