Results 151 to 160 of about 984,485 (282)

Biocatalytic Synthesis of Isoxazolines Enabled by Cryptic Nitrile Oxide Formation by a Vanadium-Dependent Chloroperoxidase. [PDF]

Angew Chem Int Ed Engl
Sharma M, Biegasiewicz KF.
europepmc   +1 more source

Redox‐Modulated σ‐Bond Reactivity in a Radical‐Anion Dimer

Angewandte Chemie International Edition, Volume 65, Issue 44, 26 October 2026.
A radialene‐based radical anion σ‐dimer comprising an elongated C‐C bond exhibits orthogonal stimuli responsiveness. Homolytic cleavage of the dimer to the radical state is triggered by mechanical strain and high temperature. Dimer scission is also achieved via oxidation, resulting in formation of neutral radialenes.
Sushil Ranjan Bhatta, Jonathan H. Gillen, Amaya T. Jayaweera, Fuead Hasan, Diana P. Merenkov, Hai Zhao, Sepideh Asgari, Arthur H. Winter, Christopher M. Bejger   +8 more
wiley   +1 more source

Synthesis of β-D-ribofuranosylbenzazoles using nitrile oxide addition chemistry

ARKIVOC, 2012
Iain A. S. Smellie, R. Michael Paton
doaj   +1 more source

A mild oxidation of nitrile oxides: a new synthetic route to nitroso carbonyl intermediates

, 1996
Addition of N-methyl morpholine N-oxide (NMO) to a nitrile oxide solution in dichloromethane at room temperature in the presence of a diene affords nitroso carbonyl adducts in fair ...
A. GAMBA INVERNIZZI, QUADRELLI, PAOLO, P. CARAMELLA   +2 more
core  

Gold Single‐Atom Catalysts Enable Selective Shuttle Hydrochlorination of Alkynes

Angewandte Chemie International Edition, EarlyView.
Gold single‐atom catalysts on activated carbon enable heterogeneous shuttle hydrochlorination of terminal alkynes to vinyl chlorides with high chemo‐ and stereo‐selectivity thanks to cooperation between Au(I) sites and the support. The catalytic system combines broad substrate compatibility, simplified separation, and recoverability, paving the way for
Marc‐Eduard Usteri, Eva J. Meeus, Christian Zachau, Seung‐Eun Choi, Aram Bugaev, Milivoj Plodinec, Sharon Mitchell, Bill Morandi, Javier Pérez‐Ramírez   +8 more
wiley   +1 more source

Activation of Metal Complexes With Ultrasound Waves for Targeted Anticancer Therapy

Angewandte Chemie International Edition, EarlyView.
Ultrasound enables non‐invasive activation of metal‐based therapeutics deep within tumors. Acoustic cavitation can drive sonodynamic reactive oxygen species generation or mechanochemical metal–ligand bond dissociation, enabling controlled release of bioactive payloads.
Félix Grosjean, Nicolás Montesdeoca, Gilles Berger, Johannes Karges   +3 more
wiley   +1 more source

Solid phase strain promoted click'' modification of DNA via [3+2]-nitrile oxide-cyclooctyne cycloadditions

, 2013
Rapid, catalyst free, solid phase modification of DNA by strain promoted cyclooctyne-nitrile oxide click chemistry is reported; the reaction is characterised by mild conditions, occurring in an aqueous environment under atmospheric conditions at room ...
Ishwar Singh (17167363), Frances Heaney (2357815)   +1 more
core  

Synthesis of novel 1,2,4-oxadiazole-isoxazoline hybrids and their in silico potential with adenosine receptors. [PDF]

Beilstein J Org Chem
Mohammed PS, Dalo MKS, Yazıcı OC, Yildirim M, Sağırlı A.   +4 more
europepmc   +1 more source

Graphene Oxide-Anchored Ru-dmso Catalyst for Sustainable Nitrile Hydrolysis in an Aqueous Medium. [PDF]

Inorg Chem
Roca I, Mimouni N, Affès S, Fontrodona X, Luis JM, Romero I.   +5 more
europepmc   +1 more source

Effect of the Reduction Degree of Graphene Oxide on the Cyclization of Polyacrylonitrile in PAN/GO Composite Membranes Prepared by Phase Inversion. [PDF]

Membranes (Basel)
Fryczkowski R, Fryczkowska B.
europepmc   +1 more source