Results 141 to 150 of about 909,766 (269)
Nitrile-oxide/dipolarophile cycloaddition polymers derived from renewable feedstocks [PDF]
Polytriazoles formed by 1,3-dipolar cycloaddition have been widely reported in literature, including some derived from renewable feedstocks. The analogous nitrile oxide-alkyne cycloaddition has received limited attention as a polymerisation technique ...
Jones, Nyle Owen Saul
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Angewandte Chemie, EarlyView.Introducing [Co(CN)6]3− defects into CoNi Prussian Blue analogues exposes square‐planar Ni–N4 active sites, leading to remarkable H2O2 selectivity during the electrochemical oxygen reduction reaction in alkaline media. ABSTRACT Decentralized electrosynthesis of hydrogen peroxide (H2O2) via the two‐electron oxygen reduction reaction (2e− ORR) offers a ...
Kai Sun +4 more
wiley +2 more sources
Angewandte Chemie, EarlyView.Merging silylium‐ion and palladium catalysis provides a mechanistically distinct route to allylsilanes by formal C–H/Si–H metathesis. Using allylsilanes as silicon proelectrophiles, various allylarenes undergo migrative silylation, selectively yielding (E)‐allylsilanes.
Longhui Duan +5 more
wiley +2 more sources
A Conserved Isoleucine Gates the Diffusion of CO and O2 to the Active Site of NiFe CO‐Dehydrogenase
Angewandte Chemie, EarlyView.A combination of protein film electrochemistry and site‐directed mutagenesis shows that isoleucine 563 (numbering of Thermococcus sp. AM4) gates the arrival of both CO and O2 to the active site of the nickel‐iron CO dehydrogenases. Mutations at this position increase the resistance to O2 at the cost of a slower reaction with CO.
Laura Opdam +7 more
wiley +2 more sources
1,3-Dipoles: Nitrile Imines, Nitrile Oxides and Nitrile Sulfides [PDF]
Synlett, 2012 openaire +1 more source
Angewandte Chemie, EarlyView.Fast charging and low‐temperature operation of lithium‐ion batteries (LIBs) are achieved by incorporating only 0.5 wt.% of a nitrile‐based additive into the commercial LP57 electrolyte. The additive enhances Li+ transport, stabilizes the solid‐electrolyte and cathode‐electrolyte interphases (SEI and CEI), and suppresses lithium plating.
Chen Liu, Zehao Cui, Arumugam Manthiram
wiley +2 more sources
Nitrile Glove Recycling Implementation Project
, 2014 The Illinois Sustainable Technology Center conducted a waste audit of their main building in February 2013. Through the process of the waste audit it was found that single use non-hazardous gloves were 13% of the waste stream.
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Angewandte Chemie, EarlyView.Supramolecular 1‐D, 2‐D, and 3‐D networks comprised of ‐(‐O═Xe(O2)‐‐)‐∞ and ‐(‐Xe(O2)O‐‐‐HO(H)‐‐)‐∞ chains coordinated to polytopic N‐base ligands were synthesized and structurally characterized by X‐ray crystallography. Their Xe‐‐‐N and Xe‐‐‐O bonds are characteristic of σ–hole bonds in which the nucleophilic Lewis base sites of the N‐ligands, H2O ...
James T. Goettel +2 more
wiley +2 more sources
Flavin Catalysts in Organic Synthesis
Angewandte Chemie, EarlyView.Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley +2 more sources
Angewandte Chemie, EarlyView.1,2‐Aryl migration involving in situ‐generated alkyl iodine(III) species proceeds through a previously unrecognized 1,2‐C/I(III) dyotropic rearrangement. Migratory aryl fluorination, acetoxylation, and alkoxylation of 2‐alkyl‐2‐aryl‐3‐iodopropanoates provide α‐heterofunctionalized products, accompanied by aryl migration from the α‐ to the β‐position ...
Chen‐Xu Liu +3 more
wiley +2 more sources