Results 261 to 270 of about 2,937,461 (378)

Electrochemical Borylation of C−C and C−Het Bonds

open access: yesChemElectroChem, Volume 12, Issue 6, March 15, 2025.
Electrosynthesis enables the cleavage and borylation of C−C, C−N, C−O, and C−S bonds, representing a significant advancement in organic chemistry. This approach offers a metal‐free strategy for synthesizing organoboron compounds, which find extensive applications across synthetic chemistry, biomedicine, and materials science.
Tsoh Lam Cheung, Hairong Lyu
wiley   +1 more source

The Azidofunctionalization of Alkenes

open access: yesChemistryEurope, EarlyView.
The azidofunctionalization of alkenes offers a powerful strategy for synthesizing nitrogen‐containing compounds by installing both an azide and a second functional group in one step. This approach, employing photoredox catalysis, transition metals, and radical methods, is efficient, selective, and versatile, with applications in pharmaceuticals and ...
Pierre Palamini, Jerome Waser
wiley   +1 more source

Rewriting Alkene Frameworks: A Practical Strategy for Nitrogen Incorporation

open access: yesChemistryEurope, EarlyView.
Morandi and team developed a metal‐free method to insert nitrogen into unactivated alkenes, forming amidines and nitriles via a transient aza‐allenium intermediate. Using mild, open‐flask conditions, the process delivers high yields and broad functional group tolerance.
Ranjini Laskar, Frank Glorius
wiley   +1 more source

Grafted Disulfide‐Linked Linear Polymers for Heterogeneous Thiyl Radical Photocatalysis

open access: yesChemistry – A European Journal, EarlyView.
Grafting a linear disulfide‐bridged polymer to a supporting polymer backbone achieved heterogeneous thiyl radical photocatalysis. The polyvinyl backbone ensures recyclability while enabling thiyl radical generation for organic transformations. Achieving ∼99% conversion for diarylalkyne photooxidation, the design strategy combines robustness, solubility,
Sunil Kumar   +4 more
wiley   +1 more source

Design of Potent Mannose‐6‐Phosphate Derivatives as Ligands for CI‐M6P/IGF2R Using Fluorescence Polarization Assay

open access: yesChemistry – A European Journal, EarlyView.
We designed and synthesized novel mannose‐6‐phosphate (M6P) derivatives to enhance their binding affinity for the CI‐M6P/IGF2 receptor, which plays a key role in lysosomal targeting. Using a fluorescence polarization assay, we evaluated di‐, tri‐, and penta‐M6P peptides and modified M6P analogs.
Lucie Mrázková   +11 more
wiley   +1 more source

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