Results 291 to 300 of about 2,975,483 (362)
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1,3-Dipolar Cycloaddition Reactions of Nitrile Oxides under "Non-Conventional" Conditions: Green Solvents, Irradiation, and Continuous Flow.

ChemPlusChem, 2020
The 1,3-dipolar cycloaddition reactions (DCs) of nitrile oxides (NOs) to alkenes and alkynes are useful methods for the synthesis of 2-isoxazolines and isoxazoles respectively, which are important classes of heterocyclic compounds in organic and ...
J. Plumet
semanticscholar   +1 more source

Polyfluorinated nitrile oxides

Chemistry of Heterocyclic Compounds, 1989
(2+3)-Cycloaddition of polyfluorinated aliphatic nitrile oxides, generated in situ, to donor dipolarophiles takes place regioselectively to give the 5-substituted isoxazolines, and is limited by the donor and steric properties of the dipolarophiles.
G. A. Sokol'skii   +3 more
openaire   +3 more sources

In Situ Generation of Nitrile Oxides from NaCl-Oxone Oxidation of Various Aldoximes and Their 1,3-Dipolar Cycloaddition.

Organic Letters, 2019
Reported is a new green protocol for the efficient in situ generation of nitrile oxides through NaCl/Oxone oxidation of aldoximes and their dipolar cycloaddition.
Guodong Zhao   +3 more
semanticscholar   +1 more source

Iterative Assembly of Nitrile Oxides and Ynamides: Synthesis of Isoxazoles and Pyrroles.

Journal of Organic Chemistry, 2019
Described is an iterative assembly of nitrile oxides and ynamides for the synthesis of isoxazoles and pyrroles. The nitrile oxides could undergo Cu(I)-free cyclization with terminal ynamides for accessing isoxazoles, which could engage in another ...
Changwei Chen, Sunliang Cui
semanticscholar   +1 more source

DABCO-mediated [3+3] cycloaddition of azomethine imines with in situ generated nitrile oxides from hydroximoyl chlorides.

Chemical Communications, 2019
A novel cross 1,3-dipolar cycloaddition between azomethine imines with in situ generated nitrile oxides has been developed. This is the first example of employing a reaction partner containing two heteroatoms in the [3+3] cycloaddition involving ...
Qing-Yun Fang   +3 more
semanticscholar   +1 more source

A nitroketene to nitrile oxide transformation

Journal of the Chemical Society, Chemical Communications, 1992
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Kappe, CO, Kollenz, G, Wentrup, C
openaire   +4 more sources

ChemInform Abstract: Cycloaddition of Nitrile Oxides to (60)Fullerene.

ChemInform, 1997
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
DA ROS, TATIANA   +5 more
openaire   +6 more sources

Addition of Nitrile Oxides to N‐Allylsaccharin. [PDF]

open access: possibleChemInform, 2005
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access the actual ChemInform Abstract, please click on HTML or PDF.
Edmunds Lukevics   +2 more
openaire   +2 more sources

Oxidative reactions of nitriles—I

Tetrahedron, 1958
Abstract Diphenyl-, cyclohexylphenyl- and methylphenyl-acetonitrile react with tert.-butyl hydroperoxide in the presence of cuprous ions at 80°. By this means, α-tert.-butylperoxydiphenyl-, α-tert.-butylperoxyphenylcyclohexyl- and α-tert.-butylperoxymethylphenyl-acetonitrile, respectively, were obtained in good to excellent yields.
George Sosnovsky, M. S. Kharasch
openaire   +3 more sources

Behaviour of nitrile oxides towards nucleophiles. Part 5. Polymerization of aromatic nitrile oxides

Journal of the Chemical Society, Perkin Transactions 1, 1979
Aromatic nitrile oxides undergo polymerization by treatment with trimethylamine in dimethyl sulphoxide. Chain lengthehing occurs via the C–O bonds, as shown by the catalytic hydrogenation of such polymers to aroylamides. The apparent degree of polymerization ranges from 15 up to ca. 100 monomer units. These polymers are quite stable in the solid state,
DE SARLO, FRANCESCO, GUARNA, ANTONIO
openaire   +3 more sources

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