Results 41 to 50 of about 239,878 (262)
An MNDO Study of Reaction of Hydrolysis of Nitrile Oxides [PDF]
63-66The addition of water to nitrile oxides (RCNO:R = H, CH3, C6H5) has been studied using the MNDO method. The potential energy hypersurface for the reactions has been investigated and the characteristics of the transition states have been determined ...
Sharma, Krishan K, Aggarwal, Anil K
core
Optical Detection of Cellular Signals at Material Interfaces
Emerging functional materials are transforming optical detection of cellular signals. This review highlights optical techniques that exploit the unique optical properties of diverse materials to detect and quantify cellular electrical, chemical, and mechanical signals, and discusses key opportunities and challenges.
Xuchen Ren +5 more
wiley +1 more source
Oxidation of α-Oxo-Oximes to Nitrile Oxides with Hypervalent Iodine Reagents
Upon reaction with PhI(OAc)2, α-oxo-aldoximes are oxidized to α-oxo-nitrile oxides, while α-oxo-ketoximes are converted into nitrile oxides via the oxidative cleavage of the carbonyl−imino σ bond.
Tim Jen (2236612) +2 more
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Bioinspired Adaptive Sensors: A Review on Current Developments in Theory and Application
This review comprehensively summarizes the recent progress in the design and fabrication of sensory‐adaptation‐inspired devices and highlights their valuable applications in electronic skin, wearable electronics, and machine vision. The existing challenges and future directions are addressed in aspects such as device performance optimization ...
Guodong Gong +12 more
wiley +1 more source
Density functional theory studies of intramolecular ene-like (or the so-called 1,3-dipolar ene) reactions between nitrile oxides and alkenes (Ishikawa, T.; Urano, J.; Ikeda, S.; Kobayashi, Y.; Saito, S. Angew. Chem., Int. Ed.
Zhi-Xiang Yu (1505023) +1 more
core +2 more sources
A large‐area, deformable high‐entropy‐ceramic (HEC)‐doped triboelectric nanogenerator with a trilayer architecture is developed, consisting of an HEC‐doped triboelectric layer, a graphite‐like textile charge‐storage layer, and stretchable carbon black electrodes.
Shengyou Li +13 more
wiley +1 more source
Synthesis of Spiroisoxazolines by 1,3-Dipolar Cycloaddition
The cycloaddition of the chiral nitrile oxide 1 to 1-R-substituted 3,3-methylene-5,5-dimethyl-2-pyrrolidinones 2 (where R is H, n-butyl-, 1,1-dimethylethoxycarbonyl-, 1-methylethenyl- and acetyl-) proceeds regioselectively under the formation of ...
Peter Ertl +3 more
doaj +1 more source
Atmospheric oxidation of nitriles
The reports of nitrile formation in actual and simulated auto emissions suggests a potential environmental hazard associated with the wide scale use of catalytic exhaust converters. Specifically, the atmospheric oxidation of nitriles is believed to occur via radical intermediates which can lead to both NO/sub x/ and CO production.
R B Timmons, R B Klemm
openaire +2 more sources
The transition from cryogenic distillation to polymeric sorbents for light hydrocarbon purification is crucial for energy and environmental sustainability. The polymeric sorbents are engineered to separate gas mixtures based on their specific properties.
Kelechi Festus +9 more
wiley +1 more source
Citation: 'nitrile oxides' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.N04150 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
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