Results 11 to 20 of about 60,877 (255)
Nickel-Catalyzed Reductive Cyanation of Aryl Halides and Epoxides with Cyanogen Bromide [PDF]
MoleculesNitriles are valuable compounds because they have widespread applications in organic chemistry. This report details the nickel-catalyzed reductive cyanation of aryl halides and epoxides with cyanogen bromide for the synthesis of nitriles.
Yu-Juan Wu +3 more
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Electrolytic Reductron of Nitriles [PDF]
NIPPON KAGAKU KAISHI, 1942 パラヂウムを以て被覆せる白金を陰極として酸性溶液にてCN-基を有する種々の型の化合物の電解還元を研究せんとし,先づ若干の代表的化合物について試みたる結果何れもCN-基は還元せられて相當するアミンを生じたり.
Masaki Ohta
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Impact of Nitriles on Bacterial Communities
Frontiers in Environmental Science, 2019 Nitriles are organic molecules with –C≡N as functional group and often toxic for living organisms. Detoxification can occur via nitrilases that degrade nitriles directly to carboxylic acids and ammonia, or with nitrile hydratases and amidases that ...
Richard Egelkamp +2 more
exaly +3 more sources
Enable biomass-derived alcohols mediated alkylation and transfer hydrogenation [PDF]
Nature CommunicationsA single-atom catalyst with generally regarded inert Zn–N4 motifs derived from ZIF-8 is unexpectedly efficient for the activation of alcohols, enabling alcohol-mediated alkylation and transfer hydrogenation. C-alkylation of nitriles, ketones, alcohols, N-
Xixi Liu +6 more
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Stereoselective synthesis of tetra- and tri-substituted alkenyl nitriles via aminative ring-opening of cyclopropenes with iron-aminyl radical [PDF]
Nature CommunicationsThe ring opening of cyclopropenes provides a compelling platform for the rapid synthesis of various polysubstituted acyclic alkenes. However, radical-mediated reactions of this type remain underexplored, and none of the existing methods have successfully
Qian Wang +4 more
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Nanocatalysts for conversion of aldehydes/alcohols/amines to nitriles: A review [PDF]
Chemical Review and Letters, 2018 This review discussed the recent advances and developments on the applications of nanocatalysts in the synthesis of organic nitrile derivatives. The review is divided into three major sections.
Sheritasadat Shahidi +4 more
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Grignard Reagent-Catalyzed Hydroboration of Esters, Nitriles, and Imines
Molecules, 2023 The reduction in esters, nitriles, and imines requires harsh conditions (highly reactive reagents, high temperatures, and pressures) or complex metal-ligand catalytic systems. Catalysts comprising earth-abundant and less toxic elements are desirable from
Hyun Ji Han +7 more
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A New Approach for the Synthesis of N-Arylamides Starting from Benzonitriles
Chemistry Proceedings, 2021 N-Arylamides are a ubiquitous component of a broad range of natural products and biologically active compounds. In this paper, a new synthetic protocol for the preparation of N-arylamides was developed via the hypervalent iodine-mediated aza-Hofmann-type
Pradip Debnath
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Role of Sulfur Compounds in Vegetable and Mushroom Aroma
Molecules, 2022 At the base of the food pyramid is vegetables, which should be consumed most often of all food products, especially in raw and unprocessed form. Vegetables and mushrooms are rich sources of bioactive compounds that can fulfill various functions in plants,
Monika A. Marcinkowska, Henryk H. Jeleń
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Life, 2022 Non-thermal plasma-seed treatments could be an environmentally friendly method to modulate plant properties. Since it remains unclear how plasmas affect seeds, RNA sequencing was used here to analyze gene transcription changes in 7-day-old Arabidopsis ...
Alexandra Waskow +3 more
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