Results 261 to 270 of about 101,712 (391)

Diverse Cyclization Pathways Between Nitriles with Active α-Methylene Group and Ambiphilic 2-Pyridylselenyl Reagents Enabled by Reversible Covalent Bonding. [PDF]

open access: yesInt J Mol Sci
Artemjev AA   +14 more
europepmc   +1 more source

Direct Activation of Sulfides by C–H Oxidation with Photoexcited Nitroarenes: Formal Manipulations of the C─S Bond

open access: yesAngewandte Chemie, EarlyView.
Photochemical anaerobic oxidation of sulfides, using nitroarenes as bifunctional reagents, enables the formal manipulation of the C─S bond. The method allows direct and selective access to versatile carbonyl compounds from largely inert sulfides by C–H oxidation, thus avoiding multistep activation by sulfur oxidation.
Valentina D. Cuomo   +2 more
wiley   +1 more source

Nickel‐Catalyzed Suzuki–Miyaura Cross‐Coupling Reaction of Aliphatic Alcohol Derivatives

open access: yesAngewandte Chemie, EarlyView.
A nickel‐catalyzed Suzuki–Miyaura coupling reaction of aliphatic mesylates is reported. This reaction provides a strategy for late‐stage functionalization of bioactive compounds that have high F(sp3). Preliminary mechanistic experiments confirm a stereoablative reaction outcome, consistent with alkyl radical intermediates.
Chloe D. Wong   +3 more
wiley   +1 more source

Interfacial Photoelectrochemistry in Organic Synthesis

open access: yesAngewandte Chemie International Edition, Accepted Article.
Photoelectrodes have traditionally enjoyed widespread attention as heterogeneous catalysts for the activation of water and CO2 in energy research, while photoelectrochemistry with homogeneous molecular catalysts dominates the activations of more complex molecules in organic synthesis.
Gabriel Chan   +4 more
wiley   +1 more source

Brassicaceae Isothiocyanate-Mediated Alleviation of Soil-Borne Diseases. [PDF]

open access: yesPlants (Basel)
Pavana Praneetha T   +4 more
europepmc   +1 more source

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