Results 271 to 280 of about 101,712 (391)
The Chemistry and Biology of the Tetrodotoxin Natural Product Family
Tetrodotoxin is a neurotoxic marine alkaloid, first isolated in 1909 from pufferfish and named after the biological order tetraodontiformes. Since its structural elucidation in 1964, it has attracted the interest of synthetic organic chemists due to its exceptional polarity, complex architecture, and important biological activity.
Benedikt Nißl+6 more
wiley +1 more source
Nitrilase GiNIT from Gibberella intermedia Efficiently Degrades Nitriles Derived from Rapeseed Meal Glucosinolate. [PDF]
Li HZ+5 more
europepmc +1 more source
This review explores the potential of mechanochemistry in the late‐stage modification of active pharmaceutical ingredients (APIs), offering a comprehensive analysis of methods designed to transform structurally complex molecular scaffolds. By examining the scope, efficiency, and mechanistic aspects of these approaches, the review highlights protocols ...
Johanna Templ, Lars Borchardt
wiley +1 more source
A one‐pot synthesis for previously unknown heavy carbynes of Group 9 metals is presented. Furthermore, in a hitherto unknown metathetical exchange reaction, the transition metal plumbylidynes were converted into the respective stannylidynes in reaction with terphenyl stannylene chloride, and the germylidynes were formed from the corresponding ...
Lennart G. Holzapfel+5 more
wiley +1 more source
Waste to Wealth: Electrochemical Innovations in Hydrogen Production From Industrial Wastewater. [PDF]
Dessie TA, Seifu LS, Dilebo WB.
europepmc +1 more source
Preparation of Aromatic Nitriles from Aromatic Primary Amines using Tetracyanonickelate (II)
Fumiyoshi URANO+2 more
openalex +2 more sources
Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles?
A new formation pathway for polycyclic aromatic nitrogen heterocycles (PANHs) has been found. The reaction of phenylnitrene and the propargyl radical leads to quinoline, proving that nitrenes are suitable precursors for nitrogen incorporation mechanisms.
Rahel Arns+6 more
wiley +1 more source
closo‐Carboranyl Analogs of β‐Arylethylamines: Direct Synthesis from Alkenes via EnT‐Catalysis
A strategy to directly synthesize closo‐carboranyl analogs of medicinal chemically important β‐arylethylamines from alkenes is reported. This reaction is enabled by the first formation of closo‐carboranyl radicals by energy transfer (EnT) catalysis and its unique mechanistic features.
Fritz Paulus+8 more
wiley +1 more source