Results 271 to 280 of about 64,062 (284)

Easier, Safer, and Greener: Unlocking the Power of Solid Reagents in Organic Reactions by Mechanochemistry

open access: yesChemistryEurope, EarlyView.
This review highlights the powerful synergy between mechanochemistry and solid reagents to replace hazardous substances traditionally used in organic synthesis. Such an approach offers a safer and more sustainable pathway for conducting organic reactions, with potential benefits in both reactivity and selectivity. The use of solid bases, acids, and gas
Adrien Gallego   +4 more
wiley   +1 more source

Ring‐opening metathesis polymerization‐Derived Organoborane Polymers as Strong Lewis Acids and Luminescent Materials

open access: yesChemistryEurope, EarlyView.
Ring‐opening metathesis polymerization offers access to borane polymers with tunable Lewis acidity, environmental stability, and luminescence. The Lewis acid strength approaches that of B(C6F5)3 when R = Cl and Ar = C6F5, high stability is ensured with chlorophenyl or naphthyl pendent groups (Ar = ClPh, Np), and strong emission is achieved with a ...
James McQuade   +5 more
wiley   +1 more source

Chemical Methods for Peptide and Protein Backbone Cleavage

open access: yesChemistryEurope, EarlyView.
Protein cleavage plays essential roles in biology and is powerful for protein manipulation and functionalization as well as in recombinant expression and purification. Here, the historical background and most recent examples of chemical methods for protein and peptide backbone cleavage are discussed (part of the figure was generated in BioRender).
Miguel Angel Alena‐Rodriguez   +1 more
wiley   +1 more source

Sulfur fluoride exchange with carbon pronucleophiles. [PDF]

open access: yesChem Sci
Novicki JR   +6 more
europepmc   +1 more source

The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions

open access: yesChemistryEurope, EarlyView.
P‐alkylation of λ3σ2‐phosphinines is hindered by weak nucleophilicity and scarce synthetic access, previously requiring multistep routes or extreme electrophiles. A direct ambient‐condition method is reported using 3,5‐bis(trimethylsilyl)‐phosphinine/B(C6F5)3 with esters or iso(thio)cyanates to generate stable 1‐R‐phosphininium salts.
Samantha Frank   +6 more
wiley   +1 more source

Home - About - Disclaimer - Privacy