Potassium <i>tert</i>-butoxide mediated stereoselective/direct Mannich reaction of α-substituted-γ-lactams with <i>in situ</i> generated aryl <i>N</i>-silyl imines. [PDF]
Casselman TD+4 more
europepmc +1 more source
Interfacing B‐DNA and DNA Mimic Foldamers
Helical aromatic oligoamide DNA mimic foldamers that reproduce the shape and charge distribution of duplex B‐DNA have been interfaced with DNA duplexes by means of a new linker that serves both as a DNA hairpin and as an aromatic oligoamide unit. In the resulting chimeric molecules, the linker does not perturb the DNA duplex structure and converts the ...
Manuel Loos+10 more
wiley +1 more source
Optical Enantiodifferentiation of Chiral Nitriles. [PDF]
Formen JSSK, Wolf C.
europepmc +1 more source
Photocatalytic [3 + 2]-annulation via sodium tetraarylborate: a fundamental approach for synthesizing 1,4,2-diazaborole analogs. [PDF]
Qin HN+5 more
europepmc +1 more source
Hexaphenyl-1,2-Diphosphonium Dication [Ph<sub>3</sub>P-PPh<sub>3</sub>]<sup>2+</sup>: Superacid, Superoxidant, or Super Reagent? [PDF]
Dankert F+9 more
europepmc +1 more source
Synthesis of a novel nanomagnetic N4 bis schiff base complex of copper(ii) as an efficient catalyst for click synthesis of tetrazoles. [PDF]
Hsu CY+7 more
europepmc +1 more source
An Update: Enzymatic Synthesis for Industrial Applications
Biocatalysis has become a sustainable and cost‐competitive alternative to established chemical synthesis, enabling the enzyme‐based production of not only commodity chemicals but (non‐natural) amino acids, (rare) sugars, as well as synthetic nucleotides.
Thomas Bayer+4 more
wiley +1 more source
A focus on phosphinophosphination of apolar bonds by a structurally constrained P-P bonded system. [PDF]
Hannah TJ, Chitnis SS.
europepmc +1 more source
Reactivity of Pnictaalumenes Towards 1,3‐Dipole Molecules
Pnictaalumenes with a Pn═Al multiple bonds undergo azide or diazoalkene insertions rather than [3+2] cycloadditions. This results in AlN2P heterocycles, which show a great structural variety depending on the sterics of the azide. With TMS‐diazoalkane, thermal rearrangements afford rare cyanidoaluminates. Abstract Alkynes undergo 1,3‐dipolar cyclization
Tim Wellnitz+7 more
wiley +1 more source