Results 21 to 30 of about 60,877 (255)

Microwave Activation in Fe-Catalyzed Reaction of Binor-S with Nitriles

Chemistry Proceedings, 2022
An efficient catalytic system consisting of 20 mol. % FeCl3·6H2O and 20 mol. % trifluoromethanesulfonic acid for the amidation of binor-S in a solution of toluene with organic nitriles under the action of microwave irradiation at 100 °C for 30 min was ...
Kseniya S. Frolova, Aigul V. Akhmerova, Tat’yana P. Zosim, Ilfir R. Ramazanov   +3 more
doaj   +1 more source

Progress of Enantioselective Nitrile Biotransformations in Organic Synthesis

CHIMIA, 2009
Recent progress of enantioselective biotransformations of nitriles including various functionalized nitriles, ?-hydroxy and ?-amino nitriles, oxirane- and aziridine-containing carbonitriles is summarized in this short review article.
Mei-Xiang Wang
doaj   +1 more source

Antifungal Activity of Glucosinolate-Derived Nitriles and Their Synergistic Activity with Glucosinolate-Derived Isothiocyanates Distinguishes Various Taxa of Brassicaceae Endophytes and Soil Fungi

Plants, 2023
The glucosinolates of Brassicaceae plants are converted into bioactive isothiocyanates and other volatiles during a challenge by pathogens and other biotic stressors.
Zsolt Szűcs, Tamás Plaszkó, Eszter Bódor, Hajnalka Csoma, Lajos Ács-Szabó, Attila Kiss-Szikszai, Gábor Vasas, Sándor Gonda   +7 more
doaj   +1 more source

NaY Zeolite: A Useful Catalyst for Nitrile Hydrolysis

Molecules, 2000
The NaY zeolite catalysed hydrolysis of nitriles to primary amides is reported. It is found that aryl nitriles with strong electron-withdrawing substituents and cyanopyridines are readily hydrolysed in the water suspension, while aliphatic nitriles do ...
Bogdan A. Å olaja, Borivoje Adnađević, Dejan M. Opsenica, Dragana R. Milić   +3 more
doaj   +1 more source

Composés d'addition des halogénures de niobium(V) et de tantale(V): II. Stabilité relative des composés des chlorures avec quelques éthers, sulfures et nitriles

CHIMIA, 1971
New NMR methods for the determination of relative stability constants are developed. These methods are used for the study of niobium(V) and tantalum(V) chlorides adducts with series of ethers, sulfides, and nitriles. The relative stabilities of nitriles
A. Merbach, J.-C. Bünzli
doaj   +1 more source

Supported Palladium Nanoparticles Catalyzed Intermolecular Carbopalladation of Nitriles and Organoboron Compounds

Frontiers in Chemistry, 2022
The first heterogeneous catalyzed example for the direct synthesis of aromatic ketones via intermolecular carbopalladation of aliphatic nitriles and organoboron compounds was developed.
Xin Liu, Dan Liu, Tegshi Muschin, Agula Bao, Chaolumen Bai, Yong-Sheng Bao   +5 more
doaj   +1 more source

Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species

Nature Communications, 2020
Nitriles are key intermediates in production of pharmaceuticals, agrochemicals and organic materials. Here, the authors report a nickel-catalyzed reductive cyanation of organic chlorides with CO2/NH3 and urea as cyanation reagents to afford a broad range
Yanan Dong, Peiju Yang, Shizhen Zhao, Yuehui Li   +3 more
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Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles

Nature Communications, 2022
Exploring benign and green methodologies for the synthesis of functionalized nitriles continues to attract the interest of academic and industrial chemists.
Kangkang Sun, Hongbin Shan, Helfried Neumann, Guo-Ping Lu, Matthias Beller   +4 more
doaj   +1 more source

The serendipitous effect of KF in Ritter reaction: Photo-induced amino-alkylation of alkenes

iScience, 2021
Summary: Ritter reaction has been recognized as an elegant strategy to construct the C−N bond. Its key feature is forming the carbocation for nucleophilic attack by nitriles.
Yu-Qing Guan, Xiang-Ting Min, Gu-Cheng He, Ding-Wei Ji, Shi-Yu Guo, Yan-Cheng Hu, Qing-An Chen   +6 more
doaj  

Cross-Cyclotrimerization with Two Nitriles as a Synthetic Pathway to Unsymmetrically 3,3’-Disubstituted bis(Tetrahydroisoquinolines)

Molecules, 2009
Microwave assisted CpCo(CO)2 catalyzed cross-cyclotrimerizations of 1,7,9,15-hexadecatetrayne with two different nitriles to give unsymmetrically substituted bis(tetrahydroisoquinolines) was studied.
Aneta Kadlčíková, Martin Kotora
doaj   +1 more source