Results 81 to 90 of about 43,948 (300)

Gas-Phase and Aqueous Photocatalytic Oxidation of Methylamine: The Reaction Pathways

open access: yesInternational Journal of Photoenergy, 2007
Photocatalytic oxidation (PCO) of methylamine (MA) on titanium dioxide in aqueous and gaseous phases was studied. A simple batch glass reactor for aqueous PCO and an annular continuous flow reactor for the gas-phase PCO were used.
Anna Kachina   +3 more
doaj   +1 more source

Tailored Catalytic Microenvironments Enable Efficient Electrochemical Ammonia Production

open access: yesAdvanced Science, EarlyView.
This study shows that Co2+ substitution in inverse spinel FeFeCoO4 constructs an integrated catalytic microenvironment for efficient nitrate‐to‐ammonia reduction. Jahn–Teller distortion activates Fe sites for *H generation, while hard–soft acid–base regulated dual‐metal sites optimize proton‐coupled electron transfer and intermediate adsorption ...
Qi Zhang   +8 more
wiley   +1 more source

The electron transport chains of Neisseria meningitidis [PDF]

open access: yes, 2007
Neisseria meningitidis contains c-type and b-type cytochromes. Oxidation of c-type and b-type cytochromes by oxygen was observed in both cells grown under aerobic and denitrifying conditions, whereas oxidation of cytochromes by nitrite was only seen in ...
Deeudom, Manu
core  

Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration

open access: yesAngewandte Chemie, EarlyView.
The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti   +9 more
wiley   +2 more sources

Bioinspired Interfacial Hydration Engineering via Metal–Organic Frameworks for Efficient Nitrate‐To‐Ammonia Conversion in Neutral Media

open access: yesAdvanced Science, EarlyView.
Inspired by Nitrite reductase, a metal–organic framework overlayer is introduced to regulate the interfacial hydration microenvironment on Cu electrodes, enriching hydrated K+ species that act as efficient proton donors. This strategy enables nitrate‐to‐ammonia conversion with near‐unity selectivity at industrial‐level current densities in neutral ...
Yuyin Mao   +4 more
wiley   +1 more source

Inverse kinetic isotope fractionation during bacterial nitrite oxidation [PDF]

open access: yes, 2008
Author Posting. © Elsevier B.V., 2009. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Geochimica et Cosmochimica Acta 73 (2009)
Casciotti, Karen L., Karen L. Casciotti
core   +1 more source

Bacterial nitrite production oxidizes Fe(II) bioremediating acidic abandoned coal mine drainage

open access: yesApplied and Environmental Microbiology
Passive remediation systems (PRSs) treating either acidic or neutral abandoned coal mine drainage (AMD) are colonized by bacteria that can bioremediate iron (Fe) through chemical cycling. Due to the low pH in acidic AMD, iron oxidation from soluble Fe(II)
Anna Vietmeier   +5 more
doaj   +1 more source

Strategies of Nitrosomonas europaea 19718 to counter low dissolved oxygen and high nitrite concentrations

open access: yesBMC Microbiology, 2010
Background Nitrosomonas europaea is a widely studied chemolithoautotrophic ammonia oxidizing bacterium. While significant work exists on the ammonia oxidation pathway of N.
Chandran Kartik, Yu Ran
doaj   +1 more source

Aptamer‐Directed Porous DNA Nanocomposite Hydrogel for Active Pulp Preservation: Immunomodulation, Stem Cell Recruitment and Reparative Dentinogenesis

open access: yesAdvanced Science, EarlyView.
This study presents an injectable DNA‐based porous hydrogel integrating catechol motifs and targeting aptamers for pulpitis management. Upon in situ crosslinking, the scaffold actively recruits endogenous dental pulp stem cells, restores redox homeostasis, and modulates immune responses.
Luhui Cai   +9 more
wiley   +1 more source

Glassy Carbon Electrode Modified with Nickel (II) Tetrasulfophtalocyanine Films and its Behavior as Amperometric Sensor for Nitrite

open access: yesInternational Journal of Electrochemical Science, 2014
In this work, a modification of a glassy carbon electrode with a film of Nickel (II) tetrasulfophtalocyanine (f-NiTSPc) was done, which was obtained by a continuous potential cycling in aqueous solution.
Paulette Astorga   +3 more
doaj   +1 more source

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