Results 141 to 150 of about 2,873,864 (246)

Modular Access to α‐Tertiary Amines: Electrochemical Tandem Di‐Functionalization of Olefins With Ammonia Surrogates and Amino Acids

open access: yesAngewandte Chemie, EarlyView.
A metal‐ and oxidant‐free electrochemical multicomponent di‐functionalization strategy that rapidly converts 1,1‐disubstituted alkenes into α‐tertiary primary amines with simultaneous installation of bio‐relevant sulfur or selenium motifs was devised for late‐stage functionalization. ABSTRACT Quaternary carbon centers, especially those bearing nitrogen,
Adrija Ghosh   +4 more
wiley   +2 more sources

Nitrogen Radical Photocatalysed Reduction of Nitrous Oxide

open access: yesAngewandte Chemie, EarlyView.
This work offers the first example of reduction of the potent greenhouse gas N2O to the benign products N2 and O(Bpin)2 using a nitrogen‐based catalyst. The active catalyst is shown to be a nitrogen‐based radical which operates under photocatalytic conditions.
Reece Lister‐Roberts   +2 more
wiley   +2 more sources

Organocatalytic Asymmetric Annulation of 2-Aminophenyl-Derived α,β-Unsaturated Systems: Access to Chiral Benzene-fused Nitrogen-containing Heterocycles

open access: yes
Nitrogen-containing heterocycles are ubiquitous structural motifs in biologically active natural products, pharmaceuticals, and functional molecules. Among them, benzene-fused nitrogen-containing heterocycles, particularly quinoline-derived frameworks ...
Minhyeok Jeon, Sung-Gon Kim
core   +1 more source

Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces

open access: yesAngewandte Chemie, EarlyView.
Hydroxyl‐functionalized dicarbaporphyrinoid polymers synthesized on Au(111) enable tunable oxygen‐mediated connectivity under UHV conditions. Thermal activation yields one‐dimensional hydroxyl‐terminated polymers that can selectively evolve into either covalently‐linked dibenzo‐p‐dioxane architectures through intermolecular C–O–C coupling or two‐fold ...
Alberto Martínez‐Bajo   +14 more
wiley   +2 more sources

DIHYDRODIPYRIDOPYRAZINES: SYNTHESIS AND FUNCTIONALIZATION

open access: yesScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry, 2010
Different conceptual synthetic approaches to the elaboration of a new family of planar polynuclear nitrogen containing aromatic heterocycles – the dihydrodipyridopyrazines – are reviewed: the arynic reaction, the sequence palladium coupling reaction ...
Gérald Guillaumet   +4 more
doaj  

Enantioselective Synthesis of Spirocyclic Nitrogen-Containing Heterocycles Catalyzed by an Iridium-Containing Cytochrome. [PDF]

open access: yesJ Am Chem Soc
Xu J   +7 more
europepmc   +1 more source

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