Results 1 to 10 of about 14,461 (232)
Química Nova, 2007 Three compounds have been synthesized with formulae [3-MeRad][Ni(dmit)2] (1), [4-MeRad][Ni(dmit)2] (2) and [4-PrRad][Ni(dmit)2] (3) where [Ni(dmit)2]- is an anionic pi-radical (dmit = 1,3-dithiol-2-thione-4,5-dithiolate) and [3-MeRad]+ is 3-N ...
Mauro Cesar Dias +6 more
doaj +1 more source
A novel profluorescent dinitroxide for imaging polypropylene degradation [PDF]
, 2008 Free-radical processes underpin the thermo-oxidative degradation of polyolefins. Thus, to extend the lifetime of these polymers, stabilizers are generally added during processing to scavenge the free radicals formed as the polymer degrades.
Fairfull-Smith, Kathryn E. +4 more
core +2 more sources
A triplet biradical with double bidentate sites based on tert-butyl pyridyl nitroxide as a candidate for strong ferromagnetic couplers [PDF]
, 2018 We synthesised a new biradical, 34bpybNO, having two chelating radical sites and demonstrated its crystal structure and ground triplet nature. Frozen-solution magnetic measurement and electron spin resonance results revealed a strong intramolecular ...
Atsushi Okazawa +3 more
core +2 more sources
Profluorescent Fluoroquinolone-Nitroxides for Investigating Antibiotic–Bacterial Interactions
Antibiotics, 2019 Fluorescent probes are widely used for imaging and measuring dynamic processes in living cells. Fluorescent antibiotics are valuable tools for examining antibiotic–bacterial interactions, antimicrobial resistance and elucidating antibiotic modes of
Anthony D. Verderosa +3 more
doaj +1 more source
Synthesis of Nitroxide-Annulated Carbocycles and Heterocycles [PDF]
, 2012 New, pyrroline nitroxide annulated lactones, polycycles, and maleimide were synthesized by classical and microwave-assisted methodology. We report the application of the metathesis reaction in the presence of nitroxide yielding a pyrroline nitroxide ...
Berente, Zoltán +4 more
core +1 more source
Molecules, 2022 A new ground triplet biradical 2′,4′,6′-triisopropylbiphenyl-3,5-diyl bis(tert-butyl nitroxide) (iPr3BPBN) was prepared and characterized by means of room-temperature ESR spectroscopy displaying a zero-field splitting pattern together with a half-field ...
Saki Ito +2 more
doaj +1 more source
EPR Study of Spin Labeled Brush Polymers in Organic Solvents [PDF]
, 2011 Spin-labeled polylactide brush polymers were synthesized via ring-opening metathesis polymerization (ROMP), and nitroxide radicals were incorporated at three different locations of brush polymers: the end and the middle of the backbone, and the end of ...
Burts, Alan O. +7 more
core +2 more sources
eXPRESS Polymer Letters, 2014 Polymer brushes with 2,2,6,6-tetramethyl-4-piperidyl methacrylate (TMPM) units, grafted on the cross-linked polystyrene (PS) microspheres, were synthesized via surface-initiated ARGET (activators regenerated by electron transfer) ATRP (atom transfer ...
S. J. Liu +5 more
doaj +1 more source
Electropolymerized Polythiophenes Bearing Pendant Nitroxide Radicals [PDF]
ACS Macro Letters, 2016 We report a facile way to synthesize polythiophenes carrying pendant 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) radicals, here called PTATs, by electropolymerization in boron trifluoride diethyl etherate (BFEE). The spacing between the TEMPO radical and the polythiophene backbone is varied by an alkyl spacer (n = 2, 4, 6), and the electronic and ...
Fei, Li +3 more
openaire +2 more sources
Synthesis and potential use of 1,8-naphthalimide type O-1(2) sensor molecules [PDF]
, 2013 New double (fluorescent and spin) sensor molecules containing 4-amino substituted 1,8-naphthalimide as a fluorophore and a sterically hindered amine (pre-nitroxide) or pyrroline nitroxide as a quencher and radical capturing moiety were synthesized.
Bognár +41 more
core +1 more source