A Computational Journey across Nitroxide Radicals: From Structure to Spectroscopic Properties and Beyond [PDF]
Molecules, 2021 Nitroxide radicals are characterized by a long-lived open-shell electronic ground state and are strongly sensitive to the chemical environment, thus representing ideal spin probes and spin labels for paramagnetic biomolecules and materials.
Vincenzo Barone +3 more
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Keep Your TEMPO Up: Nitroxide Radicals as Sensors of Intermolecular Interactions [PDF]
MoleculesThis study examines experimental data on the influence of the surrounding medium and non-covalent interactions on the isotropic hyperfine coupling constant, Aiso(14N), of the stable nitroxide radical 2,2,6,6-Tetramethylpiperidin-1-yl)oxyl (TEMPO) in ...
Ilya G. Shenderovich
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Strategies for the Synthesis of Yardsticks and Abaci for Nanometre Distance Measurements by Pulsed EPR [PDF]
Molecules, 2014 Pulsed electron paramagnetic resonance (EPR) techniques have been found to be efficient tools for the elucidation of structure in complex biological systems as they give access to distances in the nanometre range.
Silvia Valera, Bela E. Bode
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Towards Metabolic Organic Radical Contrast Agents (mORCAs) for Magnetic Resonance Imaging [PDF]
MoleculesWe report two conjugates of gem-diethyl pyrroline nitroxide radicals with D-mannosamine as potential metabolic organic radical contrast agents, mORCAs, circumventing the need for biorthogonal reactions.
Shuyang Zhang +8 more
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Study of Molecular Dimer Morphology Based on Organic Spin Centers: Nitronyl Nitroxide Radicals [PDF]
MoleculesIn this work, in order to investigate the short-range interactions between molecules, the spin-magnetic unit nitronyl nitroxide (NN) was introduced to synthesize self-assembly single radical molecules with hydrogen bond donors and acceptors.
Dongdong Wei +6 more
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Magnetic Mixed Micelles Composed of a Non-Ionic Surfactant and Nitroxide Radicals Containing a D-Glucosamine Unit: Preparation, Stability, and Biomedical Application [PDF]
Pharmaceutics, 2019 Metal-free magnetic mixed micelles (mean diameter: < 20 nm) were prepared by mixing the biocompatible non-ionic surfactant Tween 80 and the non-toxic, hydrophobic pyrrolidine-N-oxyl radicals bearing a D-glucosamine unit in pH 7.4 phosphate-buffered ...
Kota Nagura +11 more
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Magnetic Resonance Letters, 2022 Although stimuli-responsive polymers have appeared as promising materials for drug administration, the effectiveness of these materials on various bioinspired stimuli is still open for dispute.
Md Alim Uddin, Haojie Yu, Li Wang
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Fluorinated Organic Paramagnetic Building Blocks for Cross-Coupling Reactions
Molecules, 2020 New stable polyfluorinated nitroxide radicals for use in cross-coupling reactions, namely, N-tert-butyl-N-oxyamino-2,3,5,6-tetrafluoro-4-iodobenzene and N-tert-butyl-N-oxyamino-2,3,5,6-tetrafluoro-4-ethynylbenzene, were prepared from perfluoroiodobenzene.
Larisa V. Politanskaya +5 more
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2-Imidazoline Nitroxide Derivatives of Cymantrene
Molecules, 2022 The 2-imidazoline nitroxide derivatives of cymantrene—2-(η5-cyclopentadienyl)tricarbonylmanganese(I)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl (NNMn) and 2-(η5-cyclopentadienyl)tricarbonylmanganese(I)-4,4,5,5-tetramethyl-4,5-dihydro-1H ...
Kseniya Maryunina +11 more
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Recovery of Cognitive Dysfunction via Orally Administered Redox-Polymer Nanotherapeutics in SAMP8 Mice. [PDF]
PLoS ONE, 2015 Excessively generated reactive oxygen species are associated with age-related neurodegenerative diseases. We investigated whether scavenging of reactive oxygen species in the brain by orally administered redox nanoparticles, prepared by self-assembly of ...
Pennapa Chonpathompikunlert +5 more
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