Results 31 to 40 of about 10,849 (224)

Ab Initio Study of Some Persistent Nitroxide Radicals

open access: yesCHIMIA, 2008
Stable free radicals have a variety of applications. Particularly, the aminoxyl group is frequently used in spin-labeling experiments. Nitroxides may also exhibit intriguing chiral and magnetic properties, and can be of interest for studies of ...
L'uboš Horný   +2 more
doaj   +1 more source

Computational study of radicals derived from hydroxyurea and its methylated analogues. [PDF]

open access: yes, 2012
Structural and electronic properties and chemical fate of free radicals generated from hydroxyurea (HU) and its methylated analogues N-methylhydroxyurea (NMHU) and O-methylhydroxyurea (OMHU) are of utmost importance for their biological and ...
Birus, Mladen   +4 more
core   +1 more source

Comparative characteristics of sterically hindered phenols and nitroxide radicals as stabilizers of polyethylene photodegradation

open access: yesAdvanced Engineering Research, 2019
Introduction. Polymeric materials (PM) are increasingly used in various industries and agriculture. Under the action of UV light, PM are destroyed. UV stabilizers are used to protect PM from photodegradation.
I. Yu. Zhukova   +3 more
doaj   +1 more source

An Orally Administered Redox Nanoparticle That Accumulates in the Colonic Mucosa and Reduces Colitis in Mice [PDF]

open access: yes, 2012
Background & AimsDrugs used to treat patients with ulcerative colitis are not always effective because of nonspecific distribution, metabolism in the gastrointestinal tract, and side effects. We designed a nitroxide radical-containing nanoparticle (RNPO)
Matsui Hirofumi   +6 more
core   +1 more source

Crystals as Rockets: Modulation of the Salient Temperature in Cocrystals by Solvent Mixture Composition

open access: yesAngewandte Chemie, EarlyView.
Compositionally engineered mixed solvated cocrystals enable modulation of thermosalient actuation. Guest ratio controls thermosalient temperature and propulsion intensity, providing a tunable platform for designing crystalline systems that exhibit stimuli‐responsive mechanical motion.
Ernesto A. Hernández‐Morales   +5 more
wiley   +2 more sources

Fluorescence quenching of aromatic hydrocarbons by nitroxide radicals: a mechanismatic study

open access: yesInternational Journal of Photoenergy, 1999
The fluorescence quenching of phenanthrene (Phen), 9-cyanophenanthrene (CPhen), 9-cyanoanthracene (CA), perylene (Per), 9,10-dicyanoanthracene (DCA), and 9,10-diphenylanthracene (DPA) using stable nitroxide radicals as quenchers has been studied by ...
Tarek A. Fayed   +2 more
doaj   +1 more source

Studies on the antioxidative activity of red pigments in Italian-type dry-cured ham [PDF]

open access: yes, 2003
Aqueous phosphate buffer extracts and acetone/water extracts of pigments from Parma ham were assessed as antioxidants by (1) electron spin resonance spectroscopy using a spin probing technique to evaluate their efficiencies as scavengers of free radicals,
Adamsen, Christina E.   +3 more
core   +1 more source

2-(Fluoromethyl)-4,7-dimethoxy-1-methyl-1H-benzimidazole

open access: yesMolbank, 2020
Selectfluor (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)) substitutes the TEMPO free radical with fluorine on 4,7-dimethoxy-1-methyl-2-{[(2,2,6,6-tetramethylpiperidin-1-yl)oxy]methyl}-1H-benzimidazole to give the title
Patrick Kielty   +3 more
doaj   +1 more source

Antioxidant activity of wines and related matters studied by EPR spectroscopy

open access: yesCzech Journal of Food Sciences, 2008
Antioxidant activity and free radicals were studied in various parts of Vitis vinifera plant in vivo and in wines using EPR spectroscopy. Antioxidative properties of polyphenolic substances play an important role for the evaluation of quality of natural ...
Pavel STOPKA   +6 more
doaj   +1 more source

DFT Study of Nitroxide Radicals. 1. Effects of solvent on structural and electronic characteristics of 4-amino-2,2,5,5-tetramethyl-3-imidazoline-N-oxyl

open access: yes, 2003
Imidazoline-based nitroxide radicals are often used as spin probes for medium acidity and polarity in different systems. In this work, using the density functional theory (DFT) approach, we have studied how physico-chemical characteristics (geometry ...
Ikryannikova, Larissa N.   +2 more
core   +1 more source

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