Results 161 to 170 of about 23,008 (222)

Self‐Immolative Poly(Benzyl Ether)s: Design Principles and Controlled Depolymerization

open access: yesChemistry – A European Journal, EarlyView.
Unzipping to Sustainability: This Concept article explores the thermodynamic design of quinone‐methide (QM)‐based poly(benzyl ether)s (PBEs). It explains how a low ceiling temperature (Tc), QM stability, and an entropic gain drive rapid depolymerization (“unzipping”) of PBEs into monomers.
Ji Woo Kim, Yewon Kang, Hyungwoo Kim
wiley   +1 more source

The Radical Chemistry of 2,3‐Diguanidinopyridines: Coordination and Visible‐Light Photochemistry

open access: yesChemistry – A European Journal, EarlyView.
Substitution at the pyridine core of 2,3‐diguanidinopyridines was used to develop novel redox‐active molecules with three interconvertible redox states. They are applied as redox‐active ligands in coordination chemistry. Visible‐light irradiation of the pyridine N‐benzylated molecules leads to photoconversion to a higher‐energetic isomer.
Hanna Koepcke   +3 more
wiley   +1 more source

N‐Boron‐Functionalized Anionic N‐Heterocyclic Carbenes (NBA‐NHCs)—A Case Study

open access: yesChemistry – A European Journal, EarlyView.
The synthesis and characterization of a new family of N‐boron‐functionalized anionic N‐heterocyclic carbenes (NBA‐NHCs), IiPrB(CN)3−, IiPr(C2F5)BF2−, IMesB(CN)3−, and IMes(C2F5)BF2−, is reported. ABSTRACT The synthesis and characterization of a new family of N‐boron‐functionalized anionic NHCs (NBA‐NHCs), IiPrB(CN)3− (5), IiPr(C2F5)BF2− (6), IMesB(CN)3−
Sophie Mann   +3 more
wiley   +1 more source

A cascade synthesis of 2-aminothiochromones from 2-fluorophenyl ketone and thiocarbonyldiimidazole. [PDF]

open access: yesBeilstein J Org Chem
Zhang K   +9 more
europepmc   +1 more source

Directed evolution of an enantiocomplementary S<sub>N</sub>Arase reveals divergent catalytic features. [PDF]

open access: yesNat Commun
Lister TM   +8 more
europepmc   +1 more source

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