Results 1 to 10 of about 21,712 (116)
Transetherification of 2,4-dimethoxynitrobenzene by aromatic nucleophilic substitution. [PDF]
In view of the few reports concerning aromatic nucleophilic substitution reactions featuring an alkoxy group as a leaving group, the aromatic nucleophilic substitution of 2,4-dimethoxynitrobenzene was investigated with a bulky t-butoxide nucleophile ...
Jiho Song +7 more
doaj +2 more sources
Tuning Covalent Organic Frameworks via Nucleophilic Aromatic Substitution [PDF]
A family of covalent organic frameworks (COFs) with tuned properties has been prepared through nucleophilic aromatic substitution (SNAr) from a fluorinated imine‐linked COF (COF‐F).
Óscar González‐Rosell +8 more
doaj +2 more sources
Nucleophilic aromatic substitution (SNAr) reactions can provide metal-free access to synthesize monosubstituted aromatic compounds. We developed efficient SNAr conditions for p-selective substitution of polyfluoroarenes with phenothiazine in the presence
Toshifumi Dohi, Kotaro Kikushima
exaly +3 more sources
A simple and efficient methodology for the nucleophilic aromatic substitution of nitrogen-containing fused heterocycles with interesting biological activities has been developed in an environmentally sound manner using polyethylene glycol (PEG-400) as ...
Mohammed Loubidi +2 more
exaly +3 more sources
Here we describe the preparation of 2-(4-((1H-benzo[d]imidazol-2-yl)thio)-benzylidene)-hydrazine-1-carbothioamide in two steps. In the first step, 1,3-dihydro-2H-1,3-benzimidazole-2-thione was reacted with 4-fluorobenzaldehyde in DMSO to get 4-[(1H ...
Mustafa Turki Ubeid +2 more
doaj +1 more source
Microwave-assisted synthesis of azepines via nucleophilic aromatic substitution [PDF]
A novel and efficient route has been developed to afford 5H-dipyridoazepine derivatives from primary amines and 3,3'-(Z)-ethene-1,2-di-ylbis(4-chloropyridine).
Božinović Nina +2 more
doaj +1 more source
Perfluoropyridine: Discovery, Chemistry, and Applications in Polymers and Material Science
Perfluoropyridine (PFPy) is an organofluorine compound that has been employed for a variety of applications, from straightforward chemical synthesis to more advanced functions, such as fluorinated networks and polymers. This can be directly attributed to
Ritesh Gautam +4 more
doaj +1 more source
New opportunities for the synthesis of quinoxaline derivatives
Convenient methods for the synthesis of quinoxaline derivatives with the use of nucleophilic aromatic substitution of hydrogen in heteroaromatic part of molecule in conditions of the acid catalysis were elaborated.
Olga S. Koptyaeva +4 more
doaj +1 more source
1-(2,5-Dimethoxy-4-nitrophenyl)piperidine
Treatment of the non-purified mixture of dinitro isomers obtained from the nitration of 1,4-dimethoxybenzene with piperidine led to the isolation of novel but minor adduct, 1-(2,5-dimethoxy-4-nitrophenyl)piperidine (2b) in 15% yield.
Tanjia M. Syeda +4 more
doaj +1 more source
Mechanisms of Nucleophilic Aromatic and Hetero-aromatic Substitution. Recent Developments
There are now at least five well defined mechanisms of nucleophilic aromatic and heteroaromatic substitution. Three of them, the SNAr, the benzyne and the SN1 mechanism, have been known for a long time, whereas the SRN1and the SN (ANRORC) mechanisms are
Claude F. Bernasconi
doaj +1 more source

