Results 111 to 120 of about 10,092 (232)
1,1‐and 1,2‐Diborylalkenes: Preparation and Synthetic Applications
In this review, we highlight recent advances in the synthesis and reactivity of 1,1‐diborylalkenes and 1,2‐diborylalkenes, along with various transformations leading to C‐C, C‐heteroatom, and multicomponent products. By providing a comprehensive and practical resource, this review aims to assist researchers in exploring the synthetic utility of 1,1 and
Jayaram Vankudoth +2 more
wiley +1 more source
A readily accessible, air‐ and moisture‐stable palladium precatalyst, [Pd(1‐MeNAP)(tBuBrettPhos)]OTf, enables the direct N‐arylation of NH‐sulfoximines with (hetero)aryl chlorides under exceptionally mild conditions ideal for late‐stage diversification of drug‐like scaffolds.
Sourav Manna +5 more
wiley +1 more source
Lewis Acid Catalyzed Carbonyl–Olefin Metathesis
Olefin–olefin metathesis has led to important advances in diverse fields of research, including synthetic chemistry, materials science, and chemical biology.
Jacob Ludwig, Corinna Schindler
core +1 more source
A cationic gallium(III) catalyst enables rapid construction of substituted cyclopentenes via tandem carbonyl‐ene metathesis/Friedel–Crafts coupling. Electronic tuning of alcohol electrophiles allows access to diverse, densely functionalized rings in a single operation.
Arnaud Espied +6 more
wiley +1 more source
The metathesis of methyl oleate with the WCl6-cocatalyst system was investigated. Tetra-n-butyl-stannane, tetraethylstannane and triethylaluminum were effective as cocatalysts. The optimum reaction condition was considerably different from that for the metathesis of internal alkene having no functional group.
Kazuaki ICHIKAWA, Kazuo FUKUZUMI
openaire +2 more sources
Emerging Trends in Organic Photoreactions Utilizing Disulfides
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar +3 more
wiley +1 more source
Cyclic Olefin Copolymers as Versatile Materials for Advanced Engineering Applications
Cyclic olefin copolymers (COCs) are presented as highly versatile materials combining tunable synthesis, excellent optical properties, and mechanical robustness. Their potential spans microfluidics, bioengineering, and advanced electronics, while emerging self‐healing and sustainable solutions highlight future opportunities.
Giulia Fredi +3 more
wiley +1 more source
Nanomaterial Integration at Liquid–Liquid Interfaces for Green Catalysis
Functional nanomaterials assembled at liquid–liquid interfaces create dual‐role platforms serving as emulsion stabilizers and catalytic sites, offering enhanced reaction kinetics with improved catalyst recovery and recyclability. This review examines design strategies, structure‐performance relationships, and industrial implementation prospects of ...
Bokgi Seo +6 more
wiley +1 more source
This review surveys the emerging role of copper(I) catalysis in sustainable synthesis, highlighting its exceptional capacity for monoelectronic processes. By examining the strategies based on electron, halogen, and hydrogen transfer processes (SET, XAT, and HAT, respectively), we outline key reactivity trends, design principles, and the synthetic ...
Antonio Torres‐Calis +1 more
wiley +1 more source
(Arylimido)niobium(V)–alkylidene catalysts containing pentafluorophenylimido ligand, Nb(CHR)(NC6F5)(OC6X5)(PMe3)2 (R = CMe2Ph, X = F; R = SiMe3, X = Cl), show rather low catalytic activity than the 2,6‐dihalophenylimido catalysts, Nb(CHSiMe3)(N‐2,6‐X2C6H3)(OC6X5)(PMe3)2 in ring opening metathesis polymerization (ROMP) of norbornene.
Kotohiro Nomura +4 more
wiley +1 more source

