Results 91 to 100 of about 10,092 (232)
A Synthetic Approach Toward a Brominated Oxocane Labdane Diterpenoid Isolated From
Natural Product Communications, 2020 The synthesis of a labdane oxocane epoxy-alcohol is described starting from the Wieland–Miescher ketone derivative via ring closing olefin metathesis of a diene derivative, targeting the total synthesis of a brominated oxocane labdane diterpenoid ...
Hisahiro Hagiwara +4 more
doaj +1 more source
Mechanistic and Reactivity Insights into Diboron‐Mediated NN and NN Bond Scission
European Journal of Organic Chemistry, EarlyView.This review highlights the emerging ability of diboron reagents to cleave both π‐bonded (N=N) and σ‐bonded (N—N) nitrogen–nitrogen linkages, integrating mechanistic understanding with recent synthetic applications. Diboron reagents have emerged as versatile reducing agents capable of transforming a broad range of functional groups through pathways like
Raúl Valderrama‐Callejón +2 more
wiley +1 more source
European Journal of Organic Chemistry, EarlyView.Chiral tri‐ and pentahydroxy spirocyclopentane‐indolizidines were synthesized using lithium diisopropylamide “LDA” promoted diallylation and tetrahydrofuran “THF” ring‐opening in a one‐pot procedure as a key step. The sequence leading to the targeted hydroxy‐spiroindolizidines was achieved by cis‐dihydroxylation followed by reduction of the enamine and
Paula Fraňová +6 more
wiley +1 more source
European Journal of Organic Chemistry, EarlyView.We synthesize and characterize a series of well‐defined anilido–imine Fe(II) alkyl complexes that demonstrate high activity and selectivity in the cyclohydroamination of unprotected primary amines tethered to unactivated alkenes. By tuning the steric and electronic parameters of the anilido–imine ligand, we develop a catalyst that outperforms ...
Hui Dong +5 more
wiley +1 more source
Design and synthesis of ruthenium indenylidene-based catalysts for olefin metathesis
, 2013 As part of a European wide effort to develop metathesis catalysts for use in fine chemical and pharmaceutical compound synthesis, this study focuses on the design and synthesis of ruthenium based catalysts for olefin metathesis.
Urbina-Blanco, César A.
core
Química Nova, 2005 The olefin metathesis reaction allows the exchange of complex alkyl units between two olefins, with the formation of a new olefinic link and a sub-product olefin usually ethylene.
Daniel Frederico +2 more
doaj +1 more source
Macromolecular Rapid Communications, EarlyView.It is reported the design of biobased sustainable, smart, and functional adhesives achieved dispersing recycled carbon fibers into biobased epoxy monomer. ABSTRACT The development of sustainable, smart, and functional adhesives is crucial in advancing environmentally friendly materials.
Alberto Cellai +6 more
wiley +1 more source
Diverse reactivity of maleimides in polymer science and beyond
Polymer International, Volume 74, Issue 4, Page 296-306, April 2025.This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick +2 more
wiley +1 more source
Molecular Iodine-Catalyzed Carbonyl-Olefin Metathesis
, 2018 The carbonyl-olefin metathesis reaction is a synthetically valuable transformation that could facilitate rapid functional group interconversion and construction of new organic structures.
Kevin, Liyanto +5 more
core +1 more source
Olefin metathesis in multiblock copolymer synthesis
Beilstein Journal of Organic Chemistry, 2019 Multiblock copolymers constitute a basis for an emerging class of nanomaterials that combine various functional properties with durability and enhanced mechanical characteristics. Our mini-review addresses synthetic approaches to the design of multiblock
Maria L. Gringolts +3 more
doaj +1 more source