Results 91 to 100 of about 20,349 (227)
Diverse reactivity of maleimides in polymer science and beyond
Polymer International, Volume 74, Issue 4, Page 296-306, April 2025.This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick +2 more
wiley +1 more source
Synthesis and Activity of Six-Membered Cyclic Alkyl Amino Carbene–Ruthenium Olefin Metathesis Catalysts [PDF]
, 2020 Ru–cyclic alkyl amino carbene (Ru–CAAC) olefin metathesis catalysts perform extraordinarily in metathesis macrocyclization and ethenolysis, but previous studies have been limited to the use of five-membered CAAC (CAAC-5) ligands.
Grubbs, Robert H. +4 more
core
Intramolecular C−H Activation of a Bisphenolate(benzene)-Ligated Titanium Dibenzyl Complex. Competing Pathways Involving α-Hydrogen Abstraction and σ-Bond Metathesis [PDF]
, 2010 A titanium dibenzyl complex featuring a ligand with two phenolates linked by a benzene-1,3-diyl group was found to undergo thermal decomposition to give toluene and a cyclometalated dimeric complex. The thermal decomposition followed first-order kinetics
Bercaw, John E. +2 more
core +2 more sources
Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents
Polymer International, EarlyView.The process of anionic polymerization of β‐myrcene in hydrocarbon solvents was examined by kinetic studies and quantum chemical calculations. Abstract The kinetics of anionic polymerization of β‐myrcene initiated by sec‐butyllithium were examined in saturated and unsaturated hydrocarbon solvents, i.e. cyclohexane, cyclohexene, 4‐vinylcyclohexene and dl‐
Alexander Rösler +4 more
wiley +1 more source
Olefin Metathesis Reaction in Water and in Air Improved by Supramolecular Additives
Molecules, 2015 A range of water-immiscible commercially available Grubbs-type precatalysts can be used in ring-closing olefin metathesis reaction in high yields. The synthetic transformation is possible in pure water under ambient conditions.
Jasmine Tomasek +3 more
doaj +1 more source
The Chemical Record, EarlyView.This review highlights recent advances in the use of organic carbonates, dimethyl carbonate (DMC), diethyl carbonate (DEC), and propylene carbonate (PC), as solvents in organic synthesis. Based on over seventy studies from the past 6 years, it shows their application in different organic reaction types, emphasizing their role in safer and more ...
Gabriela T. Quadros +5 more
wiley +1 more source
Recent Advances in Carbonyl–Olefin and Carbonyl–Alkyne Metathesis Reactions
ChemistryEuropeCarbonyl–olefin and carbonyl–alkyne metathesis reactions are powerful strategies for the formation of carbon–carbon bonds, offering access to structurally diverse molecules.
Komal Kalonia +2 more
doaj +1 more source
Metathesis access to monocyclic iminocyclitol-based therapeutic agents
Beilstein Journal of Organic Chemistry, 2011 By focusing on recent developments on natural and non-natural azasugars (iminocyclitols), this review bolsters the case for the role of olefin metathesis reactions (RCM, CM) as key transformations in the multistep syntheses of pyrrolidine-, piperidine ...
Ileana Dragutan +5 more
doaj +1 more source
Journal of Japan Oil Chemists' Society, 1975 Unsolvated Grignard reagents with WCl6 are effective cocatalysts in the olefin metathesis. Activity of WCl6-BuMgI in benzene medium is comparable with those derived from BuLi. The optimum ratio of BuMgI to WCl6 was 2.0, and products of Friedel-Crafts reaction were less than 3% when the ratio was more than 1.5.
Toru TAKAGI +3 more
openaire +2 more sources
Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement [PDF]
, 2009 Efficient, one-pot preparation of synthetically challenging, high molecular weight (MW), narrowly dispersed brush block copolymers and random copolymers in high conversions was achieved by ring-opening metathesis (co)polymerization (ROMP) of various ...
Grubbs, Robert H. +3 more
core +1 more source