Results 81 to 90 of about 20,349 (227)

The Influence of Various N-Heterocyclic Carbene Ligands on Activity of Nitro-Activated Olefin Metathesis Catalysts

open access: yesMolecules, 2020
A set of nitro-activated ruthenium-based Hoveyda-Grubbs type olefin metathesis catalysts bearing sterically modified N-hetero-cyclic carbene (NHC) ligands have been obtained, characterised and studied in a set of model metathesis reactions.
Michał Pieczykolan   +7 more
doaj   +1 more source

Olefin Metathesis. IV.

open access: yesJournal of Japan Oil Chemists' Society, 1976
The metathesis of methyl oleate with the WCl6-cocatalyst system was investigated. Tetra-n-butyl-stannane, tetraethylstannane and triethylaluminum were effective as cocatalysts. The optimum reaction condition was considerably different from that for the metathesis of internal alkene having no functional group.
Kazuaki ICHIKAWA, Kazuo FUKUZUMI
openaire   +2 more sources

Designing organometallic compounds for catalysis and therapy [PDF]

open access: yes, 2012
Bioorganometallic chemistry is a rapidly developing area of research. In recent years organometallic compounds have provided a rich platform for the design of effective catalysts, e.g. for olefin metathesis and transfer hydrogenation.
Abraha Habtemariam   +188 more
core   +1 more source

Biobased Epoxidized Castor Oil Covalent Adaptable Networks Adhesives Reinforced with Recycled Carbon Fibers

open access: yesMacromolecular Rapid Communications, EarlyView.
It is reported the design of biobased sustainable, smart, and functional adhesives achieved dispersing recycled carbon fibers into biobased epoxy monomer. ABSTRACT The development of sustainable, smart, and functional adhesives is crucial in advancing environmentally friendly materials.
Alberto Cellai   +6 more
wiley   +1 more source

Chemical Upcycling of Nitrile Butadiene Rubbers to Polyamines and Polyols by Chemoselective Catalytic Hydrogenation

open access: yesAngewandte Chemie, Volume 138, Issue 18, 27 April 2026.
We demonstrate here the transformation of NBR (Nitrile butadiene rubber) including post‐consumer waste sourced from nitrile gloves and o‐rings into polyamines and polyols via ruthenium catalyzed hydrogenation. ABSTRACT We report here two new approaches for the chemical recycling/upcycling of nitrile butadiene rubber (NBR) to make either polyamines or ...
Alejandra Sophia Lozano Perez   +7 more
wiley   +2 more sources

(2E,2′E)-3-(4-{[4-(4-Hydroxy-3-methoxyphenyl)but-2-en-1-yl]oxy}phenyl)-1-(2-hydroxy-4-methoxyphenyl)prop-2-en-1-one

open access: yesMolbank, 2016
A hybrid of eugenol and a chalcone has been synthesized in good yield via cross olefin metathesis. The title compound (3) was characterized by spectroscopic data including NMR, infrared, and ESI-MS.
Muhamad S. Fareza   +2 more
doaj   +1 more source

Olefin Metathesis. I.

open access: yesJournal of Japan Oil Chemists' Society, 1975
The homogeneous olefin metathesis of 2-heptene with a catalyst system of WCl6-Bu4Sn was investigated. The optimum ratios of Bu4Sn to WCl6 were in the wide range of 1.02.0, and the Friedel-Crafts products were less than 3% when the ratios were more than 1.0.
Toru TAKAGI   +4 more
openaire   +2 more sources

Tandem Olefin Metathesis/Oxidative Cyclization: Synthesis of Tetrahydrofuran Diols from Simple Olefins [PDF]

open access: yes, 2016
A tandem olefin metathesis/oxidative cyclization has been developed to synthesize 2,5-disubstituted tetrahydrofuran (THF) diols in a stereocontrolled fashion from simple olefin precursors.
Dornan, Peter K.   +2 more
core   +5 more sources

Metathesis‐Sourced Epoxides in Ring‐Opening Copolymerization: Selective Access to Degradable Polythioesters

open access: yesMacromolecular Rapid Communications, EarlyView.
Metathesis‐derived cyclopentene epoxides enable strictly alternating, scrambling‐free ring‐opening copolymerization with phthalic thioanhydride, yielding well‐defined polythioesters with molecular weights up to ∼38 kg/mol. Their performance extends to oxygen‐based anhydrides and selective terpolymerizations. Direct comparisons with all‐oxygen analogues
Niracha Tangyen   +3 more
wiley   +1 more source

Acceptorless Dehydrogenative Polymerization

open access: yesAngewandte Chemie, Volume 138, Issue 18, 27 April 2026.
Acceptor‐less dehydrogenative polymerization (ADP) enables the atom‐economic step‐growth synthesis of different type of polymers directly from simple alcohols, releasing H2 as the sole by‐product. This review outlines the mechanistic foundations, catalytic systems, and emerging polymer architectures of ADP, highlighting its potential as a sustainable ...
Xin Liu   +2 more
wiley   +2 more sources

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