Results 101 to 110 of about 61,363 (222)
Revisit to ()-Civetone Synthesis
The synthesis of ( Z )-civetone ( 1 ) is described starting from oleic acid ( 5 ) via a series of reactions, intermolecular olefin self-metathesis, bromination/dehydrobromination into acetylene, semi-hydrogenation and intramolecular Dieckmann ...
Hisahiro Hagiwara +4 more
doaj +1 more source
The activation mechanism of Fe-based olefin metathesis catalysts
Density functional theory calculations have been used to describe the first turnover for olefin metathesis reaction of a homogenous Fe-based catalyst bearing a N-heterocyclic carbene ligand with methoxyethene as a substrate.
Vummaleti, Sai Vikrama Chaitanya +5 more
core +1 more source
Tandem RO-/RCM-derived ester-functional poly(olefin)s as functional coating materials [PDF]
Tandem ring-opening/ring-closing metathesis (RO/RCM) polymerization was employed to access ester-functional poly(olefin)s as functional coating materials.
Santhosh Kumar Podiyanachari +3 more
doaj +1 more source
Mechanochemical ruthenium-catalyzed olefin metathesis
We describe the development of a mechanochemical approach for Ru-catalyzed olefin metathesis, including cross-metathesis and ring-closing metathesis.
Do, Jean Louis +4 more
core +1 more source
Modular and Stereoselective Synthesis of Cyclobutane β‐Amino Alcohols
Late‐stage functionalization and photoisomerization of 1,2‐azaborine leads to a general strategy for the synthesis of diversely substituted cyclobutane β‐amino alcohols. The relative stereochemistry of the resulting products is unambiguously defined by the stereospecific and stereoselective nature of the photoisomerization‐hydrogenation‐oxidation ...
Xinyu Yang +3 more
wiley +2 more sources
A bis-calixarene from olefin metathesis
A ring-closing olefin metathesis reaction of tetrakis(allyloxy)calix[4]arene gave the bis calixarene, (15E,40E,60E)-65,74-bis(prop-2-en-1-yloxy)-13,18,38,43,58,63-hexaoxadodecacyclo[28.26.8.720,36.111,45.151,55.05,57.07,12.019,24.026,64.032,37.044,49.168,
Shimelis T. Hailu +3 more
doaj +1 more source
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source
Olefin Metathesis Involving Ruthenium Enoic Carbene Complexes
Olefin Metathesis Involving Ruthenium Enoic Carbene ...
Tae-Lim Choi (1500892) +3 more
core +1 more source
The successful extension of the nickel‐catalyzed asymmetric coupling of polarized 1,3‐dienes with aldehydes to an intramolecular setting opens an efficient new entry into hydroxylated N‐heterocyclic compounds, most notably valuable tetrahydroisoquinolines.
Thilo Bender +3 more
wiley +2 more sources
Synthesis of Medium-Sized Carbocycles by Gallium-Catalyzed Tandem Carbonyl-Olefin Metathesis/Transfer Hydrogenation [PDF]
We report a catalytic tandem process involving a ring-closing carbonyl-olefin metathesis and a transfer hydrogenation. 1,4-Cyclohexadiene has been used as H2 surrogate to reduce the cyclic alkenes formed after the metathesis step. The same NHC-stabilized
Vincent, Gandon +6 more
core +1 more source

