Results 101 to 110 of about 61,363 (222)

Revisit to ()-Civetone Synthesis

open access: yesNatural Product Communications, 2012
The synthesis of ( Z )-civetone ( 1 ) is described starting from oleic acid ( 5 ) via a series of reactions, intermolecular olefin self-metathesis, bromination/dehydrobromination into acetylene, semi-hydrogenation and intramolecular Dieckmann ...
Hisahiro Hagiwara   +4 more
doaj   +1 more source

The activation mechanism of Fe-based olefin metathesis catalysts

open access: yes, 2014
Density functional theory calculations have been used to describe the first turnover for olefin metathesis reaction of a homogenous Fe-based catalyst bearing a N-heterocyclic carbene ligand with methoxyethene as a substrate.
Vummaleti, Sai Vikrama Chaitanya   +5 more
core   +1 more source

Tandem RO-/RCM-derived ester-functional poly(olefin)s as functional coating materials [PDF]

open access: yesRSC Advances
Tandem ring-opening/ring-closing metathesis (RO/RCM) polymerization was employed to access ester-functional poly(olefin)s as functional coating materials.
Santhosh Kumar Podiyanachari   +3 more
doaj   +1 more source

Mechanochemical ruthenium-catalyzed olefin metathesis

open access: yes, 2015
We describe the development of a mechanochemical approach for Ru-catalyzed olefin metathesis, including cross-metathesis and ring-closing metathesis.
Do, Jean Louis   +4 more
core   +1 more source

Modular and Stereoselective Synthesis of Cyclobutane β‐Amino Alcohols

open access: yesAngewandte Chemie, Volume 138, Issue 43, 19 October 2026.
Late‐stage functionalization and photoisomerization of 1,2‐azaborine leads to a general strategy for the synthesis of diversely substituted cyclobutane β‐amino alcohols. The relative stereochemistry of the resulting products is unambiguously defined by the stereospecific and stereoselective nature of the photoisomerization‐hydrogenation‐oxidation ...
Xinyu Yang   +3 more
wiley   +2 more sources

A bis-calixarene from olefin metathesis

open access: yesActa Crystallographica Section E, 2012
A ring-closing olefin metathesis reaction of tetrakis(allyloxy)calix[4]arene gave the bis calixarene, (15E,40E,60E)-65,74-bis(prop-2-en-1-yloxy)-13,18,38,43,58,63-hexaoxadodecacyclo[28.26.8.720,36.111,45.151,55.05,57.07,12.019,24.026,64.032,37.044,49.168,
Shimelis T. Hailu   +3 more
doaj   +1 more source

Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 40, 27 October 2026.
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu   +2 more
wiley   +1 more source

Olefin Metathesis Involving Ruthenium Enoic Carbene Complexes

open access: yes, 2016
Olefin Metathesis Involving Ruthenium Enoic Carbene ...
Tae-Lim Choi (1500892)   +3 more
core   +1 more source

Intramolecular Nickel‐Catalyzed Reductive Coupling: Enantioselective Synthesis of Tetrahydroisoquinolines and Related Heterocycles

open access: yesAngewandte Chemie, Volume 138, Issue 43, 19 October 2026.
The successful extension of the nickel‐catalyzed asymmetric coupling of polarized 1,3‐dienes with aldehydes to an intramolecular setting opens an efficient new entry into hydroxylated N‐heterocyclic compounds, most notably valuable tetrahydroisoquinolines.
Thilo Bender   +3 more
wiley   +2 more sources

Synthesis of Medium-Sized Carbocycles by Gallium-Catalyzed Tandem Carbonyl-Olefin Metathesis/Transfer Hydrogenation [PDF]

open access: yes, 2019
We report a catalytic tandem process involving a ring-closing carbonyl-olefin metathesis and a transfer hydrogenation. 1,4-Cyclohexadiene has been used as H2 surrogate to reduce the cyclic alkenes formed after the metathesis step. The same NHC-stabilized
Vincent, Gandon   +6 more
core   +1 more source

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