Results 71 to 80 of about 4,393 (185)

Template-Directed Olefin Cross Metathesis

open access: yesOrganic Letters, 2005
[reaction: see text] A template containing two secondary dialkylammonium ion recognition sites for encirclement by olefin-bearing dibenzo[24]crown-8 derivatives has been used to promote olefin cross metatheses with ruthenium-alkylidene catalysts.
Stuart J, Cantrill   +8 more
openaire   +4 more sources

Organophosphides: A New Class of Luminophore Ligands for Copper(I) Carbene Based TADF Emitters and Photocatalysts

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 13, 23 March 2026.
Dimesitylphosphide as a heavier congener of established amide ligands for charge‐transfer copper(I) complexes leads to bathochromic shift of the emission by up to 3645 cm−1 into the orange‐red (solid, polymer films) and even NIR (solution). The thermally activated delayed fluorescence exhibits high dissymmetry factors of glum = 10−2 in polystyrene.
Paul C. Ruer   +2 more
wiley   +1 more source

Olefin metathesis in multiblock copolymer synthesis

open access: yesBeilstein Journal of Organic Chemistry, 2019
Multiblock copolymers constitute a basis for an emerging class of nanomaterials that combine various functional properties with durability and enhanced mechanical characteristics. Our mini-review addresses synthetic approaches to the design of multiblock
Maria L. Gringolts   +3 more
doaj   +1 more source

trans-Ethylenedi-p-phenylene diacetate

open access: yesActa Crystallographica Section E, 2009
The centrosymmetric title compound, C18H26O4, was prepared in high yield from 4-acetoxystyrene via Ru-catalysed homo-olefin metathesis. Exclusive formation of the E-configurated isomer was observed.
Stefanie Ritter   +3 more
doaj   +1 more source

Cationic Tungsten(VI) Penta-Methyl Complex: Synthesis, Characterization and its Application in Olefin Metathesis Reaction

open access: yesOil & Gas Science and Technology, 2016
Tungsten-hexa-methyl readily reacts with B(C6F5)3 in dichloromethane and generates the corresponding well-defined cationic tungsten-penta-methyl complex which was identified precisely by 1H NMR, 13C NMR, 1H-13C NMR correlation spectroscopy.
Dey Raju   +7 more
doaj   +1 more source

Calixarene-based molecular capsule from olefin metathesis

open access: yesActa Crystallographica Section E, 2013
The reaction of tetrakis(allyloxy)calix[4]arene with the first-generation Grubbs catalyst, followed by catalytic hydrogenation, gave the novel bis-calixarene 15,20,46,51,64,69,74,79-octaoxatridecacyclo[32.28.8.83,28.113,53.122,44.09,14.021,26.038,70.040 ...
Shimelis T. Hailu   +3 more
doaj   +1 more source

trans-1,2-Bis(3,5-dimethoxyphenyl)ethene

open access: yesActa Crystallographica Section E, 2009
The title compound, C18H20O4, was prepared in high yield from 3,5-dimethoxystyrene via a Ru-catalysed homo-olefin metathesis. Exclusive formation of the E-configurated isomer was observed. Interestingly, one symmetric unit contains two molecules adopting
Stefanie Ritter   +3 more
doaj   +1 more source

Ring Expansion via Olefin Metathesis

open access: yesJournal of the American Chemical Society, 2002
Various macrocycles were prepared in one step by a novel ring-expansion method using olefin metathesis.
Lee, Choon Woo   +2 more
openaire   +3 more sources

One‐Pot Transition‐Metal‐Free Methods for the Synthesis of All Three Bonds of the Alkyne's Triple Bond

open access: yesChemistry – A European Journal, Volume 32, Issue 10, 9 March 2026.
One‐pot transition‐metal‐free methods for the synthesis of all three bonds of the alkyne's triple bond are reviewed. After analysis of several named reactions and discussion of improvements, recent advances in the synthesis of alkynes are discussed. Each section contains a proposed reaction mechanism and analysis of the strengths and weaknesses of the ...
Eugene Kim   +4 more
wiley   +1 more source

Simple activation by acid of latent Ru-NHC-based metathesis initiators bearing 8-quinolinolate co-ligands

open access: yesBeilstein Journal of Organic Chemistry, 2016
A straightforward synthesis utilizing the ring-opening metathesis polymerization (ROMP) reaction is described for acid-triggered N,O-chelating ruthenium-based pre-catalysts bearing one or two 8-quinolinolate ligands.
Julia Wappel   +4 more
doaj   +1 more source

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