Synthesis of Telechelic Polyisoprene via Ring-Opening Metathesis Polymerization in the Presence of Chain Transfer Agent [PDF]
, 2010 Telechelic polyisoprene was synthesized via the ring-opening metathesis polymerization (ROMP) of 1,5-dimethyl-1,5-cyclooctadiene (DMCOD) in the presence of cis-1,4-diacetoxy-2-butene as a chain transfer agent (CTA).
Grubbs, Robert H., Thomas, Renee M.
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The charge percolation mechanism and simulation of Ziegler–Natta polymerizations. Part VII. Effects of the distribution of chromium active centers on silica on the polymerization of ethylene [PDF]
Journal of the Serbian Chemical Society, 2008 The charge percolation mechanism (CPM) of olefin polymerization in the presence of transition metal compounds has been applied to explain the polymerization of ethylene by silica supported chromium oxide.
DRAGOSLAV STOILJKOVIC +4 more
doaj +3 more sources
Tandem ring-closing metathesis reaction with a ruthenium catalyst containing a N-heterocyclic ligand [PDF]
, 2001 The highly active catalyst 2 was used in tandem RCM to make molecules with various ring systems containing α,β-unsaturated carbonyl ...
Choi, Tae-Lim, Grubbs, Robert H.
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Nature Communications, 2018 Olefin and emulsion polymerizations are incompatible due to the water sensitivity of olefin polymerization catalysts and thus direct synthesis of semi-crystalline polyolefin latexes is difficult.
Camille Boucher-Jacobs +4 more
doaj +1 more source
Polímeros, 2014 The aim of this study was to incorporate an alpha-olefin (1-hexene or 1-dodecene) in a high cis polybutadiene chain, using a neodymium versatate/diisobutylaluminum hydride/t-butyl chloride catalyst system.
Gustavo Monteiro da Silva +4 more
doaj +1 more source
Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: precatalysts for propylene polymerization and oligomerization [PDF]
, 2008 Zirconium and titanium complexes with tridentate bis(phenolate)-donor (donor = pyridine, furan and thiophene) ligands have been prepared and investigated for applications in propylene polymerization.
Agapie, Theodor +4 more
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Chelated Ruthenium Catalysts for Z-Selective Olefin Metathesis [PDF]
, 2011 We report the development of ruthenium-based metathesis catalysts with chelating N-heterocyclic carbene (NHC) ligands that catalyze highly Z-selective olefin metathesis.
Endo, Koji, Grubbs, Robert H.
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Nature Communications, 2022 The heterogenization of homogeneous metal complexes on solid supports has a series of drawbacks that restrict their implementation in olefin polymerization, particularly for copolymerization with polar comonomers. Here the authors show an ionic anchoring
Chen Zou, Guifu Si, Changle Chen
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Ring-Expansion Metathesis Polymerization: Catalyst-Dependent Polymerization Profiles [PDF]
, 2009 Ring-expansion metathesis polymerization (REMP) mediated by recently developed cyclic Ru catalysts has been studied in detail with a focus on the polymer products obtained under varied reaction conditions and catalyst architectures.
Boydston, Andrew J. +6 more
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Advanced Functional Materials, EarlyView.Cu‐based catalysts as a cornerstone in advancing sustainable energy technologies are fully reviewed in this manuscript, highlighting their potential in photo‐ and electrocatalysis. It includes metallic copper, copper oxides, copper sulfides, copper halide perovskites, copper‐based metal–organic frameworks (MOFs), and covalent organic frameworks (COFs),
Jéssica C. de Almeida +16 more
wiley +1 more source