Results 111 to 120 of about 42,436 (244)
Mit „c‐OMPD“ entdeckten wir eine bislang unbekannte fünfgliedrige Lactolstruktur, die durch Homoaldolkondensation des zentralen Metaboliten Brenztraubensäure entsteht. Wir zeigen, dass das Cyclisierungsgleichgewicht für die Funktion von OMPD als MRT‐basierte pH‐Sonde von entscheidender Bedeutung ist, und erreichen erstmals eine 13C‐Polarisation von >5 %
Juanita Ferreira +9 more
wiley +1 more source
Orcas (Orcinus orca) have a worldwide distribution and as apex predators feed on a wide variety of prey, including marine mammals, seabirds, sea turtles, cephalopods, teleost fish and elasmobranchs.
Kathryn A. Ayres +3 more
doaj +1 more source
THz‐EPR spectroscopy provides direct access to the low‐lying electronic structure and spin–phonon coupling in iron(II) spin crossover (SCO) complexes. Quantification of the high‐spin fraction (γHS$\gamma _{\text{HS}}$) and subtle shifts in magnetic transitions reveal the influence of the surrounding lattice and enable discrimination between microscopic
Jooris Beyer +8 more
wiley +1 more source
High-resolution biologging of an Atlantic bluefin tuna captured and eaten by a supposed orca
Biologging has been used on a range of wild animals to document spectacular feats of migration and behaviour. We describe the pursuit, capture, and ingestion of an adult Atlantic bluefin tuna (Thunnus thynnus) (175 cm, estimated weight: 81 kg), which was
Jessica L. Rudd +15 more
doaj +1 more source
Background Rapid drug desensitization (RDD) is the cornerstone of managing patients with immediate drug hypersensitivity reactions (IDHR) to antineoplastic drugs in Southern Europe and the United States.
Trine Holm Rasmussen +8 more
doaj +1 more source
Discovery of the Cyclic Form of MRI pH‐Sensor Z‐OMPD Enables >5% 13C Hyperpolarization by SABRE
With “c‐OMPD”, we discovered a previously unknown 5‐membered lactol structure that arises from the homoaldol condensation of the central metabolite pyruvic acid. We demonstrate that the cyclization equilibrium is of crucial importance for OMPD's function as MRI‐based pH sensor and achieve for the first time 13C polarization levels (>5%) by SABRE in the
Juanita Ferreira +9 more
wiley +1 more source
ABSTRACT Carbon capture technologies are poised to become one of the primary focuses regarding the achievement of net‐zero emissions by the year 2050. In these technologies, particular attention is given to post‐combustion CO2 capture, which is more easily implemented at existing power stations and other industries.
Satyajit Mukherjee +3 more
wiley +1 more source
Polymer‐Based Probabilistic Bits for Thermodynamic Computing
Electropolymerized conjugated polymers function as intrinsic entropy sources for probabilistic computing. Thermally driven conformational fluctuations of pendant triphenylamine groups produce stochastic resistance dynamics that are transduced into voltage‐gated probabilistic bits following logistic transfer functions identical to those of stochastic ...
Stephen H. Foulger +7 more
wiley +1 more source

