Results 131 to 140 of about 42,436 (244)
Chemistry – A European Journal, EarlyView.A comprehensive experimental and theoretical study is presented of a family of TADF dyes. Comparing the behavior of structurally related dyes, we uncover the subtle and somewhat unexpected role of conformational degrees of freedom associated with peripheral groups that affect the delicate interplay of excited states that governs spin–orbit coupling ...
Andrea Landi +7 more
wiley +1 more source
ORCA Collections Registry Reports
, 2007 The Online Research Collections Australia (ORCA)-Registry software is a product of the Australian Partnership for Sustainable Repositories (APSR) Collection Services and Infrastructures (COSI) initiatives of 2007.
Blanden, James
core
RhodaMal Dyes: Novel Red Emissive Fluorophores as Probes for High Contrast Live‐Cell Imaging
Chemistry – A European Journal, EarlyView.Incorporation of malononitrile into the traditional rhodol framework furnishes RhodaMal (Rhoda = Rhodamine, Mal = Malononitrile;) dyes, a new class of red emissive push–pull chromophores. Conjugating them to triphenylphosphonium cation enables live cell super‐resolution STED microscopy with a 775 nm depletion laser.
A. Mavroskoufis +8 more
wiley +1 more source
The Mechanism of Visible‐Light Photochemical Rearrangements of Conjugated Amide Enolates
Chemistry – A European Journal, EarlyView.Visible light irradiation of extended enolates of N‐benzylamides leads to homolytic C─N Bond cleavage, generating a biradical. Computational and mechanistic studies suggest rapid radical recombination within a solvent cage to give either ring‐expanded or rearranged products. ABSTRACT Deprotonation of conjugated amides forms colored solutions of lithium
James Mortimer +3 more
wiley +1 more source
Phosphanyl Radicals From Bismuth‐Mediated Reactions and Sterically Encumbered Diphosphanes
Chemistry – A European Journal, EarlyView.Reactions of LiPR2 with BiCl3 selectively give diphosphanes R2P–PR2 in high yields, presumably via Bi─P homolysis. This includes challenging cases with bulky substituents R. Sterically encumbered diphosphanes release persistent phosphanyl radicals [PR2]• in thermally initiated equilibrium reactions.
Sascha Reith +3 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.The determination of spin‐states by methods like Hirshfeld atom refinement is a promising development in the field of quantum crystallography. To this end, we present x‐ray wavefunction refinement as a next step in this process, identifying the spin and translating it into a physical wavefunction.
Johannes Bartusel +3 more
wiley +1 more source
When orcas hit the rudder: what Iberian orca-boat interactions reveal about action explanations in animal cognition. [PDF]
Anim CognFrings C.
europepmc +1 more source
Cytoskeleton, EarlyView.ABSTRACT Post‐translational modifications (PTMs) to tubulin subunits in microtubule filaments are thought to comprise a component of the tubulin code that specifies microtubule functions in cell physiology and animal development. Acetylation of Lysine‐40 (K40) on α‐tubulin (αTub‐K40ac) and glutamylation of both α‐ and β‐tubulin are two tubulin PTMs of ...
Lynne Blasius +6 more
wiley +1 more source
Single-allele chromatin tracing reveals cytokine-dependent super-enhancer repositioning in CD4<sup>+</sup> T cells. [PDF]
ImmunityJay A +10 more
europepmc +1 more source