Results 51 to 60 of about 27,821 (244)
Asymmetric Synthesis of Atropisomeric Amines via Transaminase‐Catalyzed Dynamic Kinetic Resolution
A dynamic kinetic resolution approach is developed for the atroposelective synthesis of heterobiaryl primary amines. Using transaminases and leveraging Lewis acid‐base interactions to induce racemization, a variety of axially chiral primary amines are produced in high yields and enantioselectivities.
Juan M. Coto‐Cid +8 more
wiley +1 more source
Structural diversity can be generated from α,β‐unsaturated carbonyls via N‐tosylhydrazones through a one‐pot‐three‐component photochemically promoted carboborylation/allylic Suzuki sequence. The wide availability and scope regarding each of three reaction partners: carbonyls, alkylboronic acids, and aryl halides, and the functionalities available in ...
Álvaro Valdés‐Maqueda +2 more
wiley +1 more source
The heavier, the better! We report that the caesium congener is the most active and versatile catalyst amongst a full group set of well‐defined crown ether supported alkali metal diphenyl phosphides for catalytic hydrophosphination of various substrates and phosphines including aryl and alkyl phosphines.
Felix Krämer +3 more
wiley +2 more sources
Nature of the Hydrogen Bond Enhanced Halogen Bond
The factors responsible for the enhancement of the halogen bond by an adjacent hydrogen bond have been quantitatively explored by means of state-of-the-art computational methods. It is found that the strength of a halogen bond is enhanced by ca.
Susana Portela, Israel Fernández
doaj +1 more source
Copper‐Catalyzed Defluorinative Allylboration of Allenes with Trifluoromethyl Alkenes
A copper‐catalyzed borylative coupling of allenes with 1‐trifluoromethyl alkenes is reported. The reaction selectively provides synthetically versatile borylated 1,1‐difluoro‐1,5‐dienes that can be converted into a range of medicinally relevant fluorinated compounds. Mechanistic studies reveal a key role of the catalytically generated LiCl by assisting
Martín Piñeiro‐Suárez +3 more
wiley +1 more source
La configuración del ethos poético de Orfeo en cuatro variantes del mito
El mito de Orfeo posee una potencia narrativa que generó que su relato se cuente una y otra vez y que lo convirtió en un hito importante para la cultura occidental desde la antigüedad hasta nuestros días.
Ileana Kleinman
doaj +1 more source
Orfeo, Osmin and Otello: towards a theory of opera analysis [PDF]
Three diverse operatic selections are discussed in light of a new approach to opera ...
Burton, Deborah
core
Microlobiusxylon paranaensis gen. et sp. nov. (fabaceae, mimosoideae) from the pliocene-pleistocene of ituzaingó formation, paraná basin, Argentina [PDF]
A fossil wood with Fabaceae affinity from the Pliocene-Pleistocene sediments of Ituzaingó Formation is described. The silicified wood was collected at the Toma Vieja fossil locality, Paraná Basin, Argentina.
Brea, Mariana, Franco, María Jimena
core +1 more source
En este trabajo ofrecemos un acercamiento al viaje que el Orfeó Català realizó a París, como parte de la excursión artística a París y Londres en junio de 1914.
Virginia Sánchez Rodríguez
doaj +1 more source
Sustainable one‐pot synthesis of functionalized γ‐hydroxy derivatives in deep eutectic solvents. A green, sequential CC/CX bond‐forming strategy enables diverse γ‐hydroxy derivatives via Morita–Baylis–Hillman and nucleophilic functionalization in ChCl/Gly deep eutectic solvent.
Marina Ramos‐Martín +3 more
wiley +1 more source

