Results 51 to 60 of about 27,821 (244)

Asymmetric Synthesis of Atropisomeric Amines via Transaminase‐Catalyzed Dynamic Kinetic Resolution

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 2, January 2026.
A dynamic kinetic resolution approach is developed for the atroposelective synthesis of heterobiaryl primary amines. Using transaminases and leveraging Lewis acid‐base interactions to induce racemization, a variety of axially chiral primary amines are produced in high yields and enantioselectivities.
Juan M. Coto‐Cid   +8 more
wiley   +1 more source

Sequential Carboborylation–Suzuki Coupling of α,β‐Unsaturated Tosylhydrazones: A Dual CC Bond‐Forming Strategy for Molecular Diversification

open access: yesChemistryEurope, Volume 4, Issue 1, January 2026.
Structural diversity can be generated from α,β‐unsaturated carbonyls via N‐tosylhydrazones through a one‐pot‐three‐component photochemically promoted carboborylation/allylic Suzuki sequence. The wide availability and scope regarding each of three reaction partners: carbonyls, alkylboronic acids, and aryl halides, and the functionalities available in ...
Álvaro Valdés‐Maqueda   +2 more
wiley   +1 more source

Heavyweight Champion: Caesium Diorganophosphides Outperform Lighter Congeners in the Catalytic Hydrophosphination of Alkenes and Alkynes

open access: yesAngewandte Chemie, Volume 137, Issue 44, October 27, 2025.
The heavier, the better! We report that the caesium congener is the most active and versatile catalyst amongst a full group set of well‐defined crown ether supported alkali metal diphenyl phosphides for catalytic hydrophosphination of various substrates and phosphines including aryl and alkyl phosphines.
Felix Krämer   +3 more
wiley   +2 more sources

Nature of the Hydrogen Bond Enhanced Halogen Bond

open access: yesMolecules, 2021
The factors responsible for the enhancement of the halogen bond by an adjacent hydrogen bond have been quantitatively explored by means of state-of-the-art computational methods. It is found that the strength of a halogen bond is enhanced by ca.
Susana Portela, Israel Fernández
doaj   +1 more source

Copper‐Catalyzed Defluorinative Allylboration of Allenes with Trifluoromethyl Alkenes

open access: yesChemistryEurope, Volume 4, Issue 1, January 2026.
A copper‐catalyzed borylative coupling of allenes with 1‐trifluoromethyl alkenes is reported. The reaction selectively provides synthetically versatile borylated 1,1‐difluoro‐1,5‐dienes that can be converted into a range of medicinally relevant fluorinated compounds. Mechanistic studies reveal a key role of the catalytically generated LiCl by assisting
Martín Piñeiro‐Suárez   +3 more
wiley   +1 more source

La configuración del ethos poético de Orfeo en cuatro variantes del mito

open access: yesManuscrítica
El mito de Orfeo posee una potencia narrativa que generó que su relato se cuente una y otra vez y que lo convirtió en un hito importante para la cultura occidental desde la antigüedad hasta nuestros días.
Ileana Kleinman
doaj   +1 more source

Orfeo, Osmin and Otello: towards a theory of opera analysis [PDF]

open access: yes, 2004
Three diverse operatic selections are discussed in light of a new approach to opera ...
Burton, Deborah
core  

Microlobiusxylon paranaensis gen. et sp. nov. (fabaceae, mimosoideae) from the pliocene-pleistocene of ituzaingó formation, paraná basin, Argentina [PDF]

open access: yes, 2010
A fossil wood with Fabaceae affinity from the Pliocene-Pleistocene sediments of Ituzaingó Formation is described. The silicified wood was collected at the Toma Vieja fossil locality, Paraná Basin, Argentina.
Brea, Mariana, Franco, María Jimena
core   +1 more source

El Orfeó Català y sus conciertos parisinos de 1914: de la estela de una diva al triunfo de lo popular

open access: yesPopular Music Research Today, 2018
En este trabajo ofrecemos un acercamiento al viaje que el Orfeó Català realizó a París, como parte de la excursión artística a París y Londres en junio de 1914.
Virginia Sánchez Rodríguez
doaj   +1 more source

One‐Pot Morita–Baylis–Hillman/Allylic Substitution in Deep Eutectic Solvents: Access to γ‐Hydroxy Derivatives via Sequential CC and CX (X = P, N, S, B, Si) Bond Formation

open access: yesChemSusChem, Volume 19, Issue 1, January 2026.
Sustainable one‐pot synthesis of functionalized γ‐hydroxy derivatives in deep eutectic solvents. A green, sequential CC/CX bond‐forming strategy enables diverse γ‐hydroxy derivatives via Morita–Baylis–Hillman and nucleophilic functionalization in ChCl/Gly deep eutectic solvent.
Marina Ramos‐Martín   +3 more
wiley   +1 more source

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