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Organic Acids Tunably Catalyze Carbonic Acid Decomposition
The Journal of Physical Chemistry A, 2014Density functional theory calculations predict that the gas-phase decomposition of carbonic acid, a high-energy, 1,3-hydrogen atom transfer reaction, can be catalyzed by a monocarboxylic acid or a dicarboxylic acid, including carbonic acid itself. Carboxylic acids are found to be more effective catalysts than water.
Manoj, Kumar +3 more
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Organic acids and organic ions
1997The separation and quantitation of organic ions and organic acids is an important application area of capillary electrophoresis (CE). The earliest commercial form of CE, capillary isotachophoresis (ITP), has been used for determining numerous organic ions [1]. Conventional ITP, performed with discontinuous buffers in 0.2–0.5 mm i.d.
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