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Angewandte Chemie, Volume 138, Issue 25, 15 June 2026.This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis +2 more
wiley +2 more sources
Three step synthesis of single diastereoisomers of the vicinal trifluoro motif
Beilstein Journal of Organic Chemistry, 2009 A three step route to single diastereoisomers of the vicinal trifluoromethyl motif is described. The route starts from either syn- or anti-α,β-epoxy alcohols and takes a direct approach in that each of the three steps introduces a fluorine atom in a ...
Vincent A. Brunet +2 more
doaj +1 more source
All-cis 1,2,3,4,5,6-hexafluorocyclohexane is a facially polarized cyclohexane [PDF]
, 2015 This work was generously supported by the Engineering and Physical Sciences Research Council (EPSRC) and the European Research Council (ERC).The highest-energy stereoisomer of 1,2,3,4,5,6-hexafluorocyclohexane, in which all of the fluorines are ‘up’, is ...
Douglas Philp +9 more
core +1 more source
Can fluorine form triple bonds? [PDF]
, 2022 A central dogma is that fluorine is the most electro negative element in the PSE and would thusact as a pure electron acceptor. However, to some chemists it is known, that fluorine can bond induality.
Julian M., Kleber
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Organo-Transition Metal Compounds Containing Perfluorinated Ligands
, 2010 Publisher Summary This chapter discusses the effect of α-fluorine substituents on the structure and reactivity of organic ligands bound to transition-metal centers, with particular emphasis on recent chemistry of octafluorocycloocta-1,3,5,7-tetraene ...
R. Hughes
semanticscholar +1 more source
On the Ability of Bismuth to Couple Weakly Coordinating Anions
Angewandte Chemie International Edition, EarlyView.Motivated by the growing number of catalytic processes based on high‐valent Bi, we investigated in silico the reductive elimination step responsible for the coupling of weakly coordinating anions. Relativistic contributions appeared to be decisive to the electronic description of the intermediates involved in this process.
Lucas Mele +3 more
wiley +1 more source
Fluorine chemistry at the millennium : fascinated by fluorine / [PDF]
, 2000 This volume brings together contributions by leading researchers covering a wide scope so characteristic of fluorine chemistry. It was in 1986 that the centennial of the isolation of fluorine by Moissan was celebrated, and much was said at the time about
Banks, R. E.(Ronald Eric),
core
Chemistry – A European Journal, EarlyView.Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
Elemental fluorine as a valid synthetic reagent [PDF]
, 1994 Chapter I Chapter I reviews the uses of elemental fluorine in selective organic synthesis and its use in the generation of selective electrophilic fluorinating agents.
Skinner, Christopher John
core
Chemistry – A European Journal, EarlyView.Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis +2 more
wiley +1 more source