Results 31 to 40 of about 9,709 (169)
The influence of fluorine substitution on some enzyme mediated reactions [PDF]
The replacement of a hydrogen or hydroxy group with a fluorine atom is a popular strategy to alter the activity of biologically important molecules, as their similar sizes mean that such a replacement has little steric impact.
Bridge, Colin Francis
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The Diarylprolinol Silyl Ethers: After 20 Years Still Opening New Doors in Asymmetric Catalysis
Catalysis Rules! The year 2025 marks the 20th anniversary of diarylprolinol silyl ethers in asymmetric organocatalysis. During the first decade after their discovery, these catalysts have been established as one of the most versatile tools in aminocatalysis. Although now considered mature, recent years have witnessed renewed innovation.
Enrico Marcantonio +2 more
wiley +2 more sources
Nickel‐Catalyzed Reductive Cross‐Coupling of Xanthate Esters With Aryl and Alkenyl Iodides
A nickel‐catalyzed reductive cross‐coupling of xanthate esters and aryl/alkenyl iodides is reported without the need for separate activators for the xanthate esters. The reaction utilizes a relatively low catalyst loading. Diarylmethanes with a good functional group variety can thus be synthesized indirectly from the corresponding benzylic alcohols ...
Felix Vöhringer +4 more
wiley +1 more source
To develop recycling processes for lithium‐ion batteries, wastewater treatment for the removal of organic compounds originating from the electrolyte was investigated using electro‐oxidation and ozonation. Based on the results, this paper proposes a process which combines these two methods to remove alcohols derived from the solvent and additives ...
Takumi Yasuda, Tetsuya Uda
wiley +1 more source
Aplicações sinteticas de enzimas imobiliadas em organo-gel e gel de agar [PDF]
Dissertação (Mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas.As microemulsões água-em-óleo (água + óleo + surfactante) podem ser utilizadas para formar géis elásticos e termoreversíveis pela adição de gelatina.
Queiroz, Neide
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(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh +5 more
wiley +2 more sources
Redox‐active guanidines, comprising guanidino‐functionalized aromatics (GFAs) and redox‐active urea azines (RAAs), are electron donors and strong Lewis and Brønsted bases that are used in several applications. They act as redox‐active ligands in bistable coordination compounds and as reagents in dehydrogenative coupling reactions and proton‐coupled ...
Hans‐Jörg Himmel
wiley +1 more source
The influence of the C-N⁺ ----- F-C charge dipole interaction in fluoro organic chemistry [PDF]
Chapter 1 introduces the discovery of elemental fluorine by H. Moissan and some uses of inorganic fluoride. Organo fluoro compounds and their place in pharmaceuticals and agrochemicals are also introduced.
Gooseman, Natalie Elizabeth Jane
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Estudos de fluorescencia em organo-gel [PDF]
Dissertação (Mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas.Um novo campo de estudo tem sido aberto com a solubilização de gelatina em microemulsão água em óleo. O sistema MBG é formado por Aerosol-OT, água e
Souza, Donizete de
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Electrophilic fluorination at saturated carbon [PDF]
Chapter 1 - Chapter 1 contains a discussion of the preparation and properties of elemental fluorine. A review of the use of elemental fluorine as a selective fluorinating in organic chemistry is given and the preparation and use of other selective ...
Parsons, Mandy
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