Results 121 to 130 of about 10,956 (235)
Phenol‐Rich Carbon Dots as Metal‐Free Nano‐Photocatalysts for [3 + 2] Cycloaddition Reactions
Phenol‐rich carbon dots can be effectively used, in combination with a proper base and the Schreiner thiourea (A), as nano‐photocatalysts to drive synthetically relevant [3 + 2] cycloaddition reactions between cyclopropyl ketones 1 and unsaturated hydrocarbons 2. Carbon dots (CDs) are unique carbon‐based nanoparticles with potential applications in the
Martina Mamone+3 more
wiley +1 more source
A green and simple method has been developed for efficient preparation of diverse annulated 2-amino-3-cyano-4H-pyran derivatives in the presence of a low loading of tetraethylammonium 2-(carbamoyl)benzoate (TEACB), as a bifunctional organocatalyst, under
Mohammad G. Dekamin+2 more
doaj +1 more source
1,3-Dicarbonyl compounds in stereoselective domino and multicomponent reactions
International audienceModern organic synthesis focuses on the discovery and the development of stereoselective multiple bond-forming transformations allowing the creation of several covalent bonds in a single operation.
Bonne, Damien+3 more
core +3 more sources
Enantiopure β‐chlorohydrins are valuable intermediates in organic synthesis, acting as chiral building blocks for obtaining biologically active compounds. This work presents a one‐pot two‐step linear sequence for the efficient deracemization of β‐chlorohydrins by combining a photocatalytic alcohol oxidation with a stereoselective carbonyl bioreduction ...
Sara Filgueira+3 more
wiley +1 more source
This work exemplifies how to make high molar mass ring opening copolymerization (ROCOP) polyesters as engineering plastics, informing upon their thermal and mechanical properties. Leading polyesters, prepared by epoxide/anhydride ROCOP, show high glass transition temperatures and tensile and flexural strengths, matching or exceeding polystyrene ...
Nora Jannsen+4 more
wiley +2 more sources
This study investigates the water solution‐derived structure of three zinc(II) based coordination polymers with 3‐(1H‐imidazol‐1‐yl)propanoate ligands by single crystal and powder X‐ray diffraction, infrared spectroscopy supported by theoretical calculations, and thermogravimetry.
Katharina Kodolitsch+5 more
wiley +1 more source
Quinone-catalyzed oxidative deformylation: synthesis of imines from amino alcohols
A new method for imine synthesis by way of quinone-catalyzed oxidative deformylation of 1,2-amino alcohols is reported. A wide range of readily accessible amino alcohols and primary amines can be reacted to provide N-protected imine products.
Xinyun Liu+4 more
doaj +1 more source
Proposal : Organokatalysatoren für die fluorige biphasische Katalyse ; Möglichkeiten der homogenen Katalyse mit anschließendem Katalysator‐Recycling [PDF]
Übertragung des Konzeptes der fluorigen biphasischen Systeme bzw. Übergangsmetallkatalyse auf die fluorige biphasische Organokatalyse. Entwicklung neuer Organokatalysatoren für dieses neuartige Katalysekonzept auf der Basis bereits bekannter Taddol ...
Koenigs, Rene M.
core
The Dihydroindeno[2,1‐c]fluorene Core: from Syntheses to Properties and Potential Applications
In the last decade, substances possessing the dihydroindeno[2,1‐c]fluorene scaffold showed interesting photo‐physical properties and other potential applications in electronics. The afore‐mentioned compounds belong to the family of five regioisomeric dihydroindenofluorenes, but unlike other ones, they possess angular or, in the case of higher congeners,
Timothée Cadart, Martin Kotora
wiley +1 more source
Neutral sp2–sp3 Diboranes: Structures, Reactivities, and Applications in Organic Synthesis
Neutral sp2–sp3 diboranes, featuring a polarized BB single bond between distinct sp2‐ and sp3‐hybridized boryl groups, possess unique structures and reactivity. Their properties have attracted significant research interest. This review explores the chemistry of neutral sp2–sp3 diboranes, highlighting recent progress in their syntheses, structural ...
Zhiqing Liu, Hairong Lyu
wiley +1 more source