Switching mesoionic carbene-organocatalysis from radical to ionic pathway through base-controlled formation of Breslow intermediates <i>versus</i> Breslow enolates. [PDF]
Jiao J +7 more
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Adaptive experimentation and optimization in organic chemistry. [PDF]
Schweidtmann AM, Schwaller P.
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Stereoselective electrochemical intramolecular imino-pinacol reaction: a straightforward entry to enantiopure piperazines. [PDF]
Gazzotti M +5 more
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Enantioselective NHC-Catalyzed Annulation via Umpolung for the Construction of Hydroxylamine Architectures with Variable Ring Sizes. [PDF]
Barańska I +4 more
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Bifunctional Monothiosquaramide-Catalyzed Enantioselective Addition of Masked Acyl Cyanide to Isatins: Umpolung Strategy for the Total Synthesis of (<i>S</i>)-(-)-Dioxibrassinin and (<i>R</i>)-(+)-Spirobrassinin. [PDF]
Reis FAA +7 more
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A promising dual catalytic "Isothiourea + X" platform: from classic ionic to radical transformations. [PDF]
Zhang B, Li Y, Ji Z, Wang J.
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Thermochemical and photochemical aerobic oxidation of benzylic alcohols in the presence of Cu(ii) nitrate, DDQ, and their combination. [PDF]
Veisi H, Rostami A, Amani K, Charabeh A.
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Three-Step One-Pot Photocatalytic Oxidation of Feedstocks and Organocatalytic Sequential Cascade to Access Enantioenriched α-Aminonitriles. [PDF]
Perulli S +7 more
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Asymmetric Mannich reaction of aromatic imines with malonates in the presence of multifunctional catalysts. [PDF]
Kriis K +5 more
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Triplet state reactivity of iminium ions in organocatalytic asymmetric [2 + 2] photocycloadditions. [PDF]
Corti V +6 more
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