Results 151 to 160 of about 2,457 (204)
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2009
Abstract The term Lewis acid catalysts generally refers to metal salts like aluminium chloride, titanium chloride and zinc chloride. Their application in asymmetric catalysis can be achieved by the addition of enantiopure ligands to these salts. However, not only metal centers can function as Lewis acids.
Oksana, Sereda +2 more
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Abstract The term Lewis acid catalysts generally refers to metal salts like aluminium chloride, titanium chloride and zinc chloride. Their application in asymmetric catalysis can be achieved by the addition of enantiopure ligands to these salts. However, not only metal centers can function as Lewis acids.
Oksana, Sereda +2 more
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Dope new organocatalysts for ATRP
Nature Reviews Chemistry, 2021A re-evaluation of the design principles of organocatalysts for atom transfer radical polymerization has led to the development of heteroatom-doped polycyclic arenes as highly active photocatalysts.
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Facile Preparation of Flavinium Organocatalysts
ChemSusChem, 2016AbstractWe developed a safe, simple, inexpensive, and environmentally benign method for preparing N(5)‐ethylated flavinium organocatalysts without using hazardous reagents or inert conditions as previously required. 5‐Ethyl‐3‐methyllumiflavinium cation was prepared from its reduced form by NaNO2‐free aerobic oxidation, which was subsequently extracted ...
Yukihiro Arakawa +4 more
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2017
This chapter provides a guide to the most popular and reliable synthetic methods used to prepare selected organocatalysts. Some very simple guiding features are suggested that may allow the reader to assess the utility of these synthetic methods based on reliability, modularity and scalability.
Aileen B. Frost +2 more
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This chapter provides a guide to the most popular and reliable synthetic methods used to prepare selected organocatalysts. Some very simple guiding features are suggested that may allow the reader to assess the utility of these synthetic methods based on reliability, modularity and scalability.
Aileen B. Frost +2 more
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N‐Heterocyclic Carbenes as Organocatalysts
Angewandte Chemie International Edition, 2007AbstractOrganocatalyzed reactions represent an attractive alternative to metal‐catalyzed processes notably because of their lower cost and benign environmental impact in comparison to organometallic catalysis. In this context, N‐heterocyclic carbenes (NHCs) have been studied for their ability to promote primarily the benzoin condensation.
Nicolas, Marion +2 more
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An Immobilized Organocatalyst for Cyanosilylation and Epoxidation.
ChemInform, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Kazuya Yamaguchi +5 more
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Polymeric chiral organocatalysts
Polymer Chemistry, 2011Incorporation of a chiral quaternary ammonium salt into a polymer allows for the preparation of a polymeric chiral organocatalyst that can be utilized in various asymmetric transformations in organic synthesis. Chiral quaternary ammonium salts are among the most important and frequently used organocatalysts.
Shinichi Itsuno +2 more
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Thiourea Based Fluorous Organocatalyst
2011This review deals with general and significant development of the fluorous organocatalysts based on thiourea. The applications of fluorous technology are briefly discussed. The implementations of thiourea based catalysts in organic synthesis are focused on in the chapter.
Yi-Bo, Huang, Wen-Bin, Yi, Chun, Cai
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Alkaloid Synthesis Using Organocatalysts
2018This chapter covers the literature since the advent, in the 21st century, of total syntheses of alkaloids using enantio- or diastereoselective organocatalytic reactions to construct the alkaloid scaffolds. The details of these alkaloid syntheses are described separately for each basic skeleton, including indole, indoline, oxindole, and piperidine ...
Hayato, Ishikawa, Shinya, Shiomi
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Chalcogenides as Organocatalysts
Chemical Reviews, 2007McGarrigle, EM +5 more
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