Results 101 to 110 of about 78,167 (269)

Novel "green" catalysts for controlled ring-opening polymerization of lactide [PDF]

open access: yes, 2010
Syntéza polylaktidu (PLA) polymerací za otevření kruhu cyklického monomeru (ROP) může být uskutečněna různými způsoby. Literatura uvádí více než 100 katalytických systémů, jejichž pomocí lze polylaktid a jiné biodegradabilní alifatické polyestery získat.
Surman, František
core  

Synthese, Kristallstruktur und Eigenschaften von Tetraaminophosphonium-iodid P(NH2)4I [PDF]

open access: yes, 1994
The title compound has been prepared starting from phosphorothionic triamide SP(NH2)3 by methylation of the sulfur atom and subsequent ammonolysis reaction in dry acetonitrile and dichloromethane, respectively, both at room temperature.
Horstmann, Stefan, Schnick, Wolfgang
core   +1 more source

Addressing Bottlenecks to Achieve High‐Energy Sodium‐Ion Cells Using Tin Anodes

open access: yesAdvanced Energy Materials, EarlyView.
The challenges in coupling high voltage cathode with Sn‐alloying anode or in anode‐free cell, using glyme based electrolytes to realize high energy Na‐ion cells are reported. Surface protection strategy such as SnO coating on Sn or trapping the parasitic species from poisoning the anode, helps improving the cyclability, with ∼100% capacity retention ...
Parth Desai   +11 more
wiley   +1 more source

Isolation of Key Organometallic Aryl-Co(III) Intermediates in Cobalt-Catalyzed C(sp2)–H Functionalizations and New Insights into Alkyne Annulation Reaction Mechanisms [PDF]

open access: yes, 2016
The selective annulation reaction of alkynes with substrates containing inert C–H bonds using cobalt as catalyst is currently a topic attracting significant interest.
Company, Anna   +7 more
core   +2 more sources

Structure and Spectroscopic Characterisation of Phenanthroline‐Based Iodobismuthate(III) Complexes Utilised for Raw Acoustic Signal Classification

open access: yesAdvanced Intelligent Discovery, EarlyView.
Memristors based on trimethylsulfonium (phenanthroline)tetraiodobismuthate have been utilised as a nonlinear node in a delayed feedback reservoir. This system allowed an efficient classification of acoustic signals, namely differentiation of vocalisation of the brushtail possum (Trichosurus vulpecula).
Ewelina Cechosz   +4 more
wiley   +1 more source

Structural Representation of Organometallics and Coordination Compounds and a Recommended Representation by Use of Dashed Lines

open access: yesMolecules, 2002
By using broken lines to represent coordination interactions in organometallic and other coordinated compounds, we can draw structures satisfying the valencies of the atoms present.
Shu-Kun Lin
doaj   +1 more source

Understanding β-Hydride Eliminations from Heteroatom Functional Groups [PDF]

open access: yes, 2011
Using density functional theory, we investigated detailed aspects of the quintessential organometallic process, β-hydride elimination (BHE). In general, we find that most BHE processes from alkyl functional group β-atoms are facile, while BHE processes ...
Goddard, William A. III   +1 more
core   +1 more source

Types and properties of metal-free catalysts for living polymerizations of biomaterials [PDF]

open access: yes, 2008
Syntéza biokompatibilních a biodegradabilních polyesterů, použitelných převážně v medicíně, využívá pro polymeraci za otevření kruhu katalyzátory na bázi kovu (např. Sn, Al atd.), které se mohou po implantaci deponovat v těle.
Repka, Martin
core  

Poly-MTO, {(CH_3)_{0.92} Re O_3}_\infty, a Conducting Two-Dimensional Organometallic Oxide [PDF]

open access: yes, 2005
Polymeric methyltrioxorhenium, {(CH_{3})_{0.92}ReO_{3}}_{\infty} (poly-MTO), is the first member of a new class of organometallic hybrids which adopts the structural pattern and physical properties of classical perovskites in two dimensions (2D).
B. L. Altshuler   +18 more
core   +4 more sources

Bioorganometallic derivatives of 4-hydrazino-benzenesulphonamide as carbonic anhydrase inhibitors: synthesis, characterisation and biological evaluation

open access: yesJournal of Enzyme Inhibition and Medicinal Chemistry, 2020
A series of bio-organometallic-hydrazones of the general formula [{(η5-C5H4)-C(R)=N–N(H)-C6H4-4-SO2NH2}]MLn(MLn = Re(CO)3, Mn(CO)3, FeCp; R=H, CH3) were prepared by reaction of formyl/acetyl organometallic precursors with 4-hydrazino-benzenesulphonamide.
Jeremie Brichet   +3 more
doaj   +1 more source

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