Immobilized CuCl2/TiO2 photocatalysts for the selective oxidation of benzyl alcohol to benzaldehyde
The photocatalytic aerobic oxidation of benzyl alcohol to benzaldehyde was investigated using free and alginate‐immobilized CuCl2 and/or TiO2 (P25) catalysts under UV irradiation. Immobilization enabled catalyst recovery and maintained high benzaldehyde selectivity but led to reduced activity due to internal oxygen diffusion limitations, which were ...
Nosaibeh Nosrati‐Ghods +3 more
wiley +1 more source
Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross‐Coupling
Reductive cross‐couplings enable efficient C–C bond formation but are limited by the heterogeneity of Zn or costly reagents like TDAE. We report arylhydrazines as inexpensive, convenient reductants for Ni‐catalyzed sp2–sp3 coupling of aryl halides and secondary alkyl iodides. Mechanistic studies support hydrazine‐mediated NiII reduction for a NiI/NiIII
Nils Kurig +5 more
wiley +2 more sources
Protective actions of 17β-estradiol and progesterone on oxidative neuronal injury induced by organometallic compounds. [PDF]
Ishihara Y +3 more
europepmc +1 more source
Stereoselective additions to alkenylphosphonium salts for the synthesis of P-stereogenic compounds. [PDF]
Chen XB, Padín D, Feringa BL.
europepmc +1 more source
Two air‐stable, photoluminescent lead oxide iodide carbodiimides, Pb9O2I8(CN2)3 and Pb16O5I14(CN2)4, were synthesized via solid‐state methods and structurally characterized, revealing heterocubane‐type units interconnected by iodide and (NCN)2‐ ligands.
Albert T. Schwarz +4 more
wiley +1 more source
Pyridine Into Pyrrole Transformation Induced Within the Confinement of the Macrocycle
This work demonstrates the nontrivial reactivity of pyridine incorporated into a porphyrin framework. The most significant achievement is the contraction of the six‐membered ring to a pyrrole ring, which is a phenomenon of great interest to researchers in this field.
Paulina Krzyszowska +5 more
wiley +2 more sources
Electro‐Mediated Redox Functionalization of Conjugated 1,3‐Dienes
This review aims at providing a comprehensive view of the emerging field of electro‐mediated functionalization of conjugated 1,3‐dienes, highlighting key developments, mechanistic insights, and remaining challenges. It highlights the efficient use of electron as the sole reagent to access highly substituted allylic compounds from simple and readily ...
Ophélie Montiège +3 more
wiley +1 more source
Stereospecific cross-coupling reactions: Programmed assembly of chiral molecules by reaction of chiral reagents. [PDF]
Liang H, Zhang X, Morken JP.
europepmc +1 more source
Molecular sieve sensors for selective detection at the nanogram level [PDF]
Bein, Thomas +3 more
core +1 more source
Multidisciplinary Preclinical Investigations on Ferrocenyl, Ruthenocenyl, and Benzyl Derivatives of Niridazole as New Drug Candidates against Schistosomiasis. [PDF]
Karpstein T +10 more
europepmc +1 more source

