Results 181 to 190 of about 78,167 (269)

Immobilized CuCl2/TiO2 photocatalysts for the selective oxidation of benzyl alcohol to benzaldehyde

open access: yesPhotochemistry and Photobiology, EarlyView.
The photocatalytic aerobic oxidation of benzyl alcohol to benzaldehyde was investigated using free and alginate‐immobilized CuCl2 and/or TiO2 (P25) catalysts under UV irradiation. Immobilization enabled catalyst recovery and maintained high benzaldehyde selectivity but led to reduced activity due to internal oxygen diffusion limitations, which were ...
Nosaibeh Nosrati‐Ghods   +3 more
wiley   +1 more source

Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross‐Coupling

open access: yesAngewandte Chemie, Volume 138, Issue 12, 16 March 2026.
Reductive cross‐couplings enable efficient C–C bond formation but are limited by the heterogeneity of Zn or costly reagents like TDAE. We report arylhydrazines as inexpensive, convenient reductants for Ni‐catalyzed sp2–sp3 coupling of aryl halides and secondary alkyl iodides. Mechanistic studies support hydrazine‐mediated NiII reduction for a NiI/NiIII
Nils Kurig   +5 more
wiley   +2 more sources

From Heterocubane Units to Extended Networks: Synthesis, Structure, and Optical Properties of Pb9O2I8(CN2)3 and Pb16O5I14(CN2)4

open access: yesZeitschrift für anorganische und allgemeine Chemie, Volume 652, Issue 5, 18 March 2026.
Two air‐stable, photoluminescent lead oxide iodide carbodiimides, Pb9O2I8(CN2)3 and Pb16O5I14(CN2)4, were synthesized via solid‐state methods and structurally characterized, revealing heterocubane‐type units interconnected by iodide and (NCN)2‐ ligands.
Albert T. Schwarz   +4 more
wiley   +1 more source

Pyridine Into Pyrrole Transformation Induced Within the Confinement of the Macrocycle

open access: yesAngewandte Chemie, Volume 138, Issue 11, 9 March 2026.
This work demonstrates the nontrivial reactivity of pyridine incorporated into a porphyrin framework. The most significant achievement is the contraction of the six‐membered ring to a pyrrole ring, which is a phenomenon of great interest to researchers in this field.
Paulina Krzyszowska   +5 more
wiley   +2 more sources

Electro‐Mediated Redox Functionalization of Conjugated 1,3‐Dienes

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 6, 17 March 2026.
This review aims at providing a comprehensive view of the emerging field of electro‐mediated functionalization of conjugated 1,3‐dienes, highlighting key developments, mechanistic insights, and remaining challenges. It highlights the efficient use of electron as the sole reagent to access highly substituted allylic compounds from simple and readily ...
Ophélie Montiège   +3 more
wiley   +1 more source

Molecular sieve sensors for selective detection at the nanogram level [PDF]

open access: yes, 1989
Bein, Thomas   +3 more
core   +1 more source

Multidisciplinary Preclinical Investigations on Ferrocenyl, Ruthenocenyl, and Benzyl Derivatives of Niridazole as New Drug Candidates against Schistosomiasis. [PDF]

open access: yesChemMedChem
Karpstein T   +10 more
europepmc   +1 more source

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