Results 181 to 190 of about 3,158,128 (352)

Rigid Ligand Environments at Beryllium, From Spectroscopic Probes to Small Molecule Activation

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Due to the high rigidity and definition of beryllium scorpionate complexes, they can be used to study metal‐pseudohalide and ‐carbon bonds in detail. Furthermore, these compounds can be used to activate small molecules and exhibit unprecedented transmetalation reactions. In beryllium scorpionate complexes, three of the four available coordination sites
Magnus R. Buchner, Chantsalmaa Berthold
wiley   +1 more source

Carbonylative Suzuki–Miyaura Coupling of 1‐Iodoglycals Mediated by the N‐Heterocyclic Carbene Catalyst PEPPSI: Preparation of C‐Acyl Glycosides

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A multicomponent carbonylative Suzuki–Miyaura reaction was developed for the synthesis of C‐acyl glycosides. Using Pyridine‐Enhanced Precatalyst Preparation, Stabilization, and Initiation (PEPPSI‐IPr) catalysis and Mo(CO)6 as a solid CO source, the reaction enables selective carbonylation of three components in synthetically useful yields, providing a ...
Eurípedes de Aguiar   +5 more
wiley   +1 more source

Enhancing the Catalytic Activity of Pd Nanocatalysts for Anion Exchange Membrane Direct Ethanol Fuel Cells by Functionalizing Vulcan XC-72 with Cu Organometallic Compounds. [PDF]

open access: yesACS Appl Nano Mater
Meléndez-González PC   +7 more
europepmc   +1 more source

Selective Catalytic Oxidation of Benzyl Alcohol to Benzaldehyde With Alkyl Allyl Carbonates and Pd(II) Allyl‐Amidinate

open access: yesHelvetica Chimica Acta, EarlyView.
A Pd(II) allyl‐amidinate complex catalyzes the selective oxidation of benzyl alcohols to aldehydes using allyl alkyl carbonates as tailored, mild oxidants. The carbonate reagent acts both as oxidant and in situ base, enabling chemoselective conversion and minimizing overoxidation under mild conditions.
Christian Ehinger   +3 more
wiley   +1 more source

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