Results 51 to 60 of about 1,629,354 (275)

The Selective Oligomerization of Ethylene Using Chromium Diphosphine Catalysts and the Synthesis and Reactivity of Group 7 Carbonyl Derivatives Relevant to Synthesis Gas Conversion [PDF]

open access: yes, 2009
The work presented in this thesis explores two distinct fields of organometallic chemistry with a common goal of selectively transforming cheap and abundant feedstocks to value-added chemicals using homogeneous catalysts.
Elowe, Paul Richard
core   +1 more source

Geometry‐Driven Whispering‐Gallery Modes in Self‐Assembled Phosphorescent Organic Microtubes

open access: yesAdvanced Optical Materials, EarlyView.
Micelles encapsulating tris(2‐phenylpyridine)iridium(III) self‐assemble into a hollow hexagonal microtube stabilized by a surface passivation layer. The hexagonal cross‐section confines circulating light along its facets, sustaining sharp whispering‐gallery resonances that guide photoluminescence emission under laser excitation.
Do Wan Kim   +10 more
wiley   +1 more source

Laser-Induced Breakdown Spectroscopy Analysis of Lithium: A Comprehensive Review

open access: yesSensors
Lithium has emerged as a pivotal material for the global energy transition, yet its supply security is challenged by limited geographical availability and growing demand.
Stefano Legnaioli   +9 more
doaj   +1 more source

Effect of Electrode Shape and Flow Conditions on the Electrochemical Detection with Band Microelectrodes

open access: yesSensors, 2018
In this work, we report the analysis of the electrochemical detection of electroactive species with band microelectrodes that operate under controlled convection.
Maher Al Khatib   +6 more
doaj   +1 more source

Hexavalent chromium release over time from a pyrolyzed Cr-bearing tannery sludge

open access: yesScientific Reports, 2023
Pyrolysis in an inert atmosphere is a widely applied route to convert tannery wastes into reusable materials. In the present study, the Cr(III) conversion into the toxic hexavalent form in the pyrolyzed tannery waste referred to as KEU was investigated ...
Lisa Ghezzi   +11 more
doaj   +1 more source

Hyperpolarization of [1‐13C]Ketoisocaproate‐d2 by Reversible Exchange with Parahydrogen Enables Profiling of Branched‐Chain‐Amino‐Acid Metabolism in Cellulo and in Vivo

open access: yesAdvanced Science, EarlyView.
We report the fast generation of biocompatible solutions of highly 13C‐hyperpolarized (≈11%) partially‐deuterated ketoisocaproate within <6 min using spin‐lock‐induced crossing and reversible exchange with parahydrogen (SLIC‐SABRE). This enables rapid detection of branched‐chain‐amino‐acid transferase 1 (BCAT1) protein expression and investigation of ...
Stefan Petersen   +18 more
wiley   +1 more source

Organometallic Chemistry in Non-Classical Environments

open access: yesCHIMIA, 2011
A summary of our on-going research on organometallic chemistry is provided with an emphasis on the function, reactivity and mechanisms of organometallic compounds in water, ionic liquids and in living systems.
Paul J. Dyson
doaj   +1 more source

Unusual DNA binding modes for metal anticancer complexes [PDF]

open access: yes, 2009
DNA is believed to be the primary target for many metal-based drugs. For example, platinum-based anticancer drugs can form specific lesions on DNA that induce apoptosis.
Pizarro, Ana M., Sadler, P. J.
core   +1 more source

1‐Azabicyclo[1.1.0]butanes (ABBs) on the Map: Mechanistic Pathways for Catalytic Ring Opening and Functionalizations

open access: yesAngewandte Chemie, EarlyView.
Catalytic strain‐release ring opening and functionalizations of 1‐azabicyclo[1.1.0]butanes (ABBs) represent a promising strategy for accessing diverse azetidine products. These transformations proceed via polar pathways, radical pathways, and hybrid mechanisms that combine both.
James Shao‐Jiun Yang   +1 more
wiley   +2 more sources

In Search of Structure’ Links Across Length Scales: Crossover Among Structural Motifs, Energetics, and Magic Systems in Subnanometer Transition Metals Clusters

open access: yesSmall Structures
Clusters of transition metal (TM) elements are becoming increasingly important in our daily lives for a wide ensemble of applications in catalysis and bio‐fields, for health, energy and environmental problems.
Ernesto Garcia‐Alfonso   +3 more
doaj   +1 more source

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