Results 61 to 70 of about 20,841 (234)

Palladacarboxamide Capping Reagents for Carbon Isotope Labeling and Pharmaceutical Diversification

Angewandte Chemie, EarlyView.
Herein, we present a method for carbon isotope labeling of arylamides via the coupling of air‐stable palladium carboxamide complexes and boronic ester/acids. A wide variety of functionalized boronic esters and acids have been coupled with simple palladium carboxamides complexes.
Daniel V. Hoffmann, Anika Schick, Lasse Kjær, Vitus J. Enemærke, Clemens Kaussler, Jens Torp, Pablo Martínez‐Pardo, Charles S. Elmore, Troels Skrydstrup   +8 more
wiley   +2 more sources

Solid Ethanol as a Renewable, Low‐Toxicity, Electron‐Beam Direct Write, and Biomedical Material

Advanced Science, EarlyView.
3D ice lithography (3DIL) enables the fabrication of intricate submicrometer objects using ethanol as a renewable starting material. This study combines process optimization, structural and material analysis, and biomedical applications, from cell culture scaffolds to the patterning of neurostimulation electrodes, demonstrating performance in both in ...
Bruno Perdigão, Bingdong Chang, Gwendoline A. E. Anand, Lechan Tao, Kayeon Kim, Anne Zebitz Eriksen, Malte Alexander Schönhoff, Guilherme Ferreira, Xiyuan Liu, Su Genelioglu, Joachim Lyngholm‐Kjærby, Neha Zahoor, Johan Ulrik Lind, Alice Bastos da Silva Fanta, Thomas Willum Hansen, Changsi Cai, Anpan Han   +16 more
wiley   +1 more source

Fast Quantification of Lithium Concentration in Non-Compliant Materials Using Laser-Induced Breakdown Spectroscopy

Applied Sciences
Although approximately half of global lithium consumption is used in the rechargeable battery industry, lithium is also in demand for other specialized applications, such as high-temperature lubricants, ceramics, glass, and pharmaceuticals.
Simona Raneri, Vincenzo Palleschi, Francesco Poggialini, Beatrice Campanella, Giulia Lorenzetti, Pilario Costagliola, Valentina Rimondi, Guia Morelli, Stefano Legnaioli   +8 more
doaj   +1 more source

A Catalytic Osmium Redox Couple Collapses Cancer Redox Balance

Advanced Science, EarlyView.
A stable Os(III)/Os(IV) redox couple is developed to disrupt the tumor cell redox balance by concurrently catalyzing ROS generation and GSH depletion. Osmium‐treated cells exhibit multiple cell death pathways, including apoptosis, ferroptosis, and immunogenic cell death.
Wan‐Qiong Huang, Tao Huang, Yiming Hao, Gui‐Feng Huang, Yi‐Lang Yan, Xin Fang, Ying Chen, Xiao‐Long Wei, Wai‐Lun Man, Wen‐Xiu Ni   +9 more
wiley   +1 more source

Formation of Gallium Monofluoride in the Coordination Sphere of Nickel

Angewandte Chemie, EarlyView.
The elusive gas‐phase species gallium monofluoride forms selectively in the coordination sphere of a nickel(II) centre as a product of C(sp3)–F bond activation, with a weakly coordinating anion as the fluorine source. The herein reported gallium monofluoride ligand acts as a very strong σ‐donor ligand at nickel and serves as a fluorine donor towards ...
Johannes Stephan, Samia Kahlal, Jean‐Yves Saillard, Marvin Mühlau, Lisa Gremmel, Christian Gemel, Roland A. Fischer   +6 more
wiley   +2 more sources

COLLOID-CHEMICAL PROPERTIES OF SILICONE SURFACTANTS USED IN THE SYNTHESIS OF POLYSTYRENE LATEXES

Тонкие химические технологии, 2016
The synthesis of polymeric suspensions with a narrow particle size distribution is an urgent problem in modern science. The resulting polymeric microspheres are applicable in various fields of chemistry, pharmaceuticals, biology and medicine.
I. A. Gritskova, A. A. Amelichev, O. A. Satskevich, A. V. Shkolnikov, A. A. Ezhova, G. A. Simakova, V. A. Vasnyov, N. A. Lobanova, B. A. Izmaylov   +8 more
doaj   +1 more source

Adaptive Coordination Engineering for Efficient and Robust H2 Release

Advanced Science, EarlyView.
β‐H elimination is a pivotal but challenging step in homogeneous formic acid dehydrogenation reactions due to strict hydride‐metal matching. By using a rationally designed Pd1Ag2 bimetallic system with adaptive Pd1‐Ag2/L2 coordination and formate bridges, it enables boosted formic acid dehydrogenation under ambient air (7.7 times higher than a Pd ...
Xiaolin Jiang, Xiaoyang Yan, Shenglong Jiang, Hongdan Zhu, Heng Wang, Xiaopeng Li, Xiaochun Zhou, Mingdong Zhou, Qian Peng   +8 more
wiley   +1 more source

A New Metal‐Ester Bonding Motif for the Synthesis of Hybrid Molecular Catalysts on Metal Oxide Supports Leads to Tunable Reactivity

Angewandte Chemie, EarlyView.
This work reports a new metal–ester bonding strategy for anchoring molecular catalysts to metal oxide supports, achieving exceptionally high surface loadings. Catalyst reactivity is predictably tuned by the support's properties, enabling control over electronic behavior and reaction pathways, thus opening new possibilities for designing highly ...
Joseph J. Kuchta III, Sarah M. Moody, Alexia M. Bradbury, D. M. S. C. Dissanayake, Laura C. Maybach, Santosh K. Balijepalli, John R. Regalbuto, Aaron K. Vannucci   +7 more
wiley   +2 more sources

Organometallic Compounds

International Journal of Pharmaceutical Research and Applications
Organometallic compounds have garnered significant attention in the field of medicinal chemistry due to their unique properties and diverse applications in treating various diseases. These compounds, characterized by the presence of metal-carbon bonds, exhibit a wide range of biological activities that make them valuable in therapeutic contexts.
Aryash Kounda, Happy Happy, Dr.Kapil Kumar Verma   +2 more
openaire   +3 more sources

Natural Antioxidants: Advancing Stability and Performance in Sustainable Biobased and Biodegradable Plastics

Compounds
The depletion of fossil fuels and environmental concerns have driven the development of sustainable materials, including bio-based and biodegradable plastics, as alternatives to conventional plastics.
Norma Mallegni, Francesca Cicogna, Elisa Passaglia, Vito Gigante, Maria-Beatrice Coltelli, Serena Coiai   +5 more
doaj   +1 more source