Results 21 to 30 of about 5,406 (201)
Molecules, 2023 A one-pot lithiation–phosphonylation procedure was elaborated as a method to prepare heteroaromatic phosphonic acids. It relied on the direct lithiation of heteroaromatics followed by phosphonylation with diethyl chlorophosphite and then oxidation with ...
Ewa Chmielewska +4 more
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Synthesis of Mixed Arylalkyl Tertiary Phosphines via the Grignard Approach
Molecules, 2022 Trialkyl and triaryl phosphines are important classes of ligands in the field of catalysis and materials research. The wide usability of these low-valent phosphines has led to the design and development of new synthesis routes for a variety of phosphines.
Ashanul Haque +4 more
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The bis(Biphenyl)phosphorus Fragment in Trivalent and Tetravalent P-Environments
Inorganics, 2021 Diaryl substituted phosphorus (III) compounds are commonly used motifs in synthesis. Although the basic synthetic routes to these molecules starting from PCl3 are well reported, sterically hindered aryl substituents can be difficult to introduce ...
Jonas Hoffmann +3 more
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Separations, 2022 A survey of the experimental equilibrium constants in solution for the mixed complexes of 4f ions with acidic (chelating) and O-donor organophosphorus ligands published in the period between 1954 and 2022 is presented.
Maria Atanassova
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The Backbone of Success of P,N-Hybrid Ligands: Some Recent Developments
Molecules, 2022 Organophosphorus ligands are an invaluable family of compounds that continue to underpin important roles in disciplines such as coordination chemistry and catalysis.
Martin B. Smith
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Homolytic substitution at phosphorus for C–P bond formation in organic synthesis
Beilstein Journal of Organic Chemistry, 2013 Organophosphorus compounds are important in organic chemistry. This review article covers emerging, powerful synthetic approaches to organophosphorus compounds by homolytic substitution at phosphorus with a carbon-centered radical. Phosphination reagents
Hideki Yorimitsu
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Origin of catalytic activity differences between phosphine and phosphine oxide-based structures in the water-crosslinkable polyalkoxysilane composition [PDF]
Polyolefins Journal, 2021 Organocatalysts have attracted enormous interest in the water-crosslinking reaction in silane-grafted polyolefins (SGPOs) system owing to their simplicity, low toxicity and environmentally benign nature compared to organotin catalysts, which are most ...
Tanaka Shohei, Kenta Adachi
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Molecules, 2018 The α-amidoalkylating properties of 1-(N-acylamino)alkyltriarylphosphonium salts with weakened Cα-P+ bond strength are discussed and examined.
Jakub Adamek +4 more
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Frontiers in Chemistry, 2023 Organophosphorus esters fulfil many industrial, agricultural, and household roles. Nature has deployed phosphates and their related anhydrides as energy carriers and reservoirs, as constituents of genetic materials in the form of DNA and RNA, and as ...
Ikenna Onyido +3 more
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