Identifying and Prioritizing Chemicals with Uncertain Burden of Exposure: Opportunities for Biomonitoring and Health-Related Research. [PDF]
BackgroundThe National Institutes of Health's Environmental influences on Child Health Outcomes (ECHO) initiative aims to understand the impact of environmental factors on childhood disease. Over 40,000 chemicals are approved for commercial use.
(Environmental influences on Child Health Outcomes)+9 more
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Descriptors for the Prediction of Partition Coefficients and Solubilities of Organophosphorus Compounds [PDF]
From literature data on partition coefficients and in some cases solubilities in nonaqueous solvents we have been able to determine Abraham descriptors for several series of organophosphorus compounds including the dialkyl- and diaryl-phosphates ...
Abraham, MH, Acree, WE
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Functionalization, Fragmentation, and Expansion of cyclo‐P4R2 Ligands
Three isolobal transition metal (TM) units are demonstrated to impact the transformation of coordinated P4 ligands in different ways. The observed reactivity primarily depends on the nature of the TM, an effect so far underexplored in phosphorus chemistry. This in‐depth analysis shines light on the underlying mechanistic principles and exploits them to
Christoph Riesinger+7 more
wiley +1 more source
Complex formation and enantioselectivity studies of triazole fungicide and organophosphorus pesticide enantiomers using capillary electrophoresis [PDF]
Several cyclodextrin modified-micellar electrokinetic chromatography (CDMEKC) methods were developed for the successful triazole fungicides separation.
Hermawan, Dadan+2 more
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Developmental Exposure of Rats to Chlorpyrifos Elicits Sex-Selective Hyperlipidemia and Hyperinsulinemia in Adulthood [PDF]
Developmental exposure to chlorpyrifos alters cell signaling both in the brain and in peripheral tissues, affecting the responses to a variety of neurotransmitters and hormones.
Barone S+5 more
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Mg Plating in Nonethereal Electrolyte Solutions: Fact or Misconception?
An overview of Mg electrochemistry in both ethereal and nonethereal electrolyte systems was provided. Comprehensive reviewing on the electrochemical Mg plating/stripping activity reaffirms that only a limited range of solvents support reversible Mg plating/stripping.
Toshihiko Mandai
wiley +1 more source
A structural, spectroscopic and theoretical study of the triphenylphosphine chalcogenide complexes of tungsten carbonyl, [W(XPPh3)(CO)5], X=O, S, Se [PDF]
The series [W(XPPh3)(CO)5], X=O, S, Se has been structurally determined by X-ray crystallography and fully characterised spectroscopically to provide data for comparing the bonding of the Ph3PX ligands to the metal.
Cook, Julian B.+2 more
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Nitrobenzene poisoning presenting as Methemoglobinemia
Consumption of toxic compounds in an attempt to commit suicide is very common. Organophosphorus compounds are the most commonly consumed and fatal poisons. Nitrobenzene consumption for suicidal purposes is very rare.
Amit A Bharadiya+4 more
doaj +1 more source
Surface‐Active Imidazolium Diorganophosphates as Catalysts for Epoxidations in Water
Imidazolium diorganophosphates are surface‐active ionic liquids, which are catalytically active in epoxidation reactions in two‐phase media using hydrogen peroxide as oxidant. The catalytic activity is ascribed to the formation of phosphorous peroxo species upon reaction of the diorganophosphate anion with H2O2.
Fabian Schmidt+5 more
wiley +1 more source
Organophosphorus-tellurium chemistry : from fundamentals to applications [PDF]
T.C. thanks the NSERC (Canada) for continuing funding. J.D.W. is grateful to the University of St Andrews for support. A.N.
Chivers, Tristram+2 more
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