Copper (II) Catalyzed Oxidative Alkoxylation of White Phosphorus. Communication 2
White phosphorus has been catalytically oxidized by oxygen in alcoholic solutions of copper (II) acetylacetonate, halides or carboxylates to yield dialkyl phosphites and trialkyl phosphates under mild reaction conditions.
R. R. Abdreimova+2 more
doaj +1 more source
Effects of Concurrent Sulphur‐ and Phosphorus Incorporation in Nickel Cyclam‐based Complexes
We investigated the concurrent presence of S, P, and N donor atoms in isocyclam frameworks and their corresponding nickel complexes to get insight into the influence of these different heteroatoms on their structural and electronic properties. Structural elucidation of the complexes revealed both octahedral and square‐planar coordination modes for Ni ...
Tatiana Guseva+6 more
wiley +1 more source
Effect of Organic Diet Intervention on Pesticide Exposures in Young Children Living in Low-Income Urban and Agricultural Communities. [PDF]
BackgroundRecent organic diet intervention studies suggest that diet is a significant source of pesticide exposure in young children. These studies have focused on children living in suburban communities.ObjectivesWe aimed to determine whether consuming ...
Aguilar Schall, Raul+7 more
core
Lethality of suicidal organophosphorus poisoning in an Indian population: exploring preventability
Background Suicide by organophosphorus poisoning is common in India. Study of factors associated with lethality may suggest methods for prevention. Methods Severity of symptoms, biochemical manifestation of poisoning, degree of lethality and the outcome ...
Kar Nilamadhab
doaj +1 more source
Porous coordination polymers (PCPs) or metal–organic frameworks (MOFs) hold promise as photocatalyst candidates for the remediation of toxic metal ions and organic pollutants. However, they often exhibit inferior removal and catalytic efficiency due to the rapid recombination of photoexcited electrons and holes.
Wenting Li+4 more
wiley +1 more source
Structure-activity correlations for organophosphorus ester anticholinesterases. Part 2: CNDO/2 calculations applied to ester hydrolysis rates [PDF]
Quantitative structure-activity relationships are presented for the hydrolysis of organophosphorus esters, RR'P(O)X, where R and R' are alkyl and/or alkoxy groups and X is fluorine, chlorine or a phenoxy group.
Golub, M. A.+3 more
core +1 more source
Synthesis and characterisation of ferrocenyl-phosphonic and -arsonic [PDF]
The ferrocene-derived acids FcCH₂CH₂E(O)(OH)₂ [4, E=P; 10, E=As; Fc=Fe(η₅-C₅H₅)(η⁵-C₅H₄)] have been synthesized by the reaction of FcCH₂CH₂Br with either P(OEt)₃ followed by hydrolysis, or with sodium arsenite followed by acidification.
Alley, Steven R., Henderson, William
core +2 more sources
Evaluation of intravenous lipid emulsion as a novel therapeutic antidote in severe organophosphorous poisoning- A prospective randomized, comparative study [PDF]
Background: Organophosphorus compounds are usually esters, amides or thiol derivatives of phosphonic acid and form a large family (>50000 compounds). The principal use of these compounds are as pesticides in agriculture, mainly as insecticides.
Shabnum Majeed, Altaf H. Malik, B.A. Dar
doaj
High pressure high temperature (HPHT) synthesis and magnetism of MSr2Y1.5Ce0.5Cu2O10 compounds with M = Ru, Mn, and Cr [PDF]
The M-1222 compounds are synthesized in near single phase form. These compounds crystallise in I4/mmm Tetragonal structure. None of the studied compound is superconducting but they asre weakly magnetic. This is first report on synthesis of Cr and Mn -1222 compounds.
arxiv
Development of inkjet inks for intelligent packaging applications. ABSTRACT Food packaging is crucial for preserving food quality, safety, and integrity while meeting consumer demands for convenience and sustainability. Innovative packaging systems can enhance the basic packaging characteristics; in particular, intelligent packaging meets the rising ...
Siyi Liu, Zhenyu Han, Xiaoyu Luo
wiley +1 more source