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A unified framework for van ‘t Hoff’s law: addressing the complexity of osmotic concentration [PDF]

open access: yesRoyal Society Open Science
The original van ‘t Hoff’s law established the theoretical foundation for osmosis but applies only to ideal solutions and membranes. To address real-world complexities (non-ideal solutions, diverse membranes, etc.), multiple variations have emerged over ...
Serena Y. Kuang   +3 more
doaj   +2 more sources

Prediction of thermodynamic properties of aqueous carbohydrates solution using the PHSC and ANN models [PDF]

open access: yesScientific Reports
In this work the Artificial Neural Network (ANN) and the Perturbed Hard Sphere Chain (PHSC) equation of state (EoS) have been utilized to estimate the osmotic coefficient, activity coefficient, and water activity of aqueous sugar solutions containing ...
Soud Khalil Ibrahim   +11 more
doaj   +2 more sources

Evaluation of energy consumption during the seawater desalination process simulated to the aqueous ternary system {NaCl + KCl}(aq) [PDF]

open access: yesE3S Web of Conferences, 2021
Energy consumption is a purely thermodynamic concept very useful in several scientific fields such as desalination, oceanography, biology, geochemistry and environmental processes, as well as in industrial applications.
Errougui Abdelkbir   +2 more
doaj   +1 more source

Structure and thermodynamics in the linear modified Poisson-Boltzmann theories in restricted primitive model electrolytes

open access: yesCondensed Matter Physics, 2021
Structure and thermodynamics in restricted primitive model electrolytes are examined using three recently developed versions of a linear form of the modified Poisson-Boltzmann equation.
L. B. Bhuiyan
doaj   +1 more source

An Evaluation of Four Electrolyte Models for the Prediction of Thermodynamic Properties of Aqueous Electrolyte Solutions [PDF]

open access: yesIranian Journal of Oil & Gas Science and Technology, 2017
In this work, the performance of four electrolyte models for prediction the osmotic and activity coefficients of different aqueous salt solutions at 298 K, atmospheric pressure and in a wide range of concentrations are evaluated. In two of these models, (
Kamalodin Momeni   +2 more
doaj   +1 more source

Experimental study on chemico-osmotic membrane behaviors of reactive MgO-activated slag-bentonite backfill in vertical cutoff walls exposed to Pb-laden groundwater

open access: yesYantu gongcheng xuebao, 2022
The reactive magnesia (MgO) is used as an alkali activator to activate granulated blast furnace slag (GGBS) to prepare alkali activated slag-bentonite-soil vertical barrier (MSBS) material.
LI Shuang-jie 1, WU Hao-liang 1, 2, FU Xian-lei 1, JIANG Ning-jun 1, WAN Jian-lei 1, LI Jiang-shan 3, DU Yan-jun 2
doaj   +1 more source

Charge Regulation and pH Effects on Thermo-Osmotic Conversion

open access: yesNanomaterials, 2022
Thermo-osmotic energy conversion using waste heat is one of the approaches to harvesting sustainable energy and reducing associated environmental impacts simultaneously. In principle, ions transport through a charged nanopore membrane under the effect of
Van-Phung Mai   +2 more
doaj   +1 more source

Experimental study and micro-mechanism analysis on chemico-osmotic membrane behavior of kaolin-bentonite

open access: yesYantu gongcheng xuebao, 2023
The semipermeable membrane behavior of clay materials can significantly delay contaminant diffusion, which is of great importance to evaluating the service performance of barriers in various landfills effectively.
ZHANG Zhihong , YANG Haowen , ZHENG Jiuzhou
doaj   +1 more source

Evidence of Many-Body Interactions in the Virial Coefficients of Polyelectrolyte Gels

open access: yesGels, 2022
Simulation studies of aqueous polymer solutions, and heuristic arguments by De Gennes for aqueous polyethylene oxide polymer solutions, have suggested that many-body interactions can give rise to the ‘anomalous’ situation in which the second osmotic ...
Ferenc Horkay, Jack F. Douglas
doaj   +1 more source

Prediction of the Osmotic/activity Coefficients of Alkali Hydroxide Electrolytes [PDF]

open access: yesIndustrial & Engineering Chemistry Research, 2020
Osmotic/activity coefficients are one of the most fundamental and important properties of electrolyte solutions. There is currently no reliable means of predicting these properties from first principles without relying on extensive fitting to experimental data. Alkali hydroxide aqueous electrolytes are a particularly important class of solutions due to
Timothy T. Duignan, X. S. Zhao
openaire   +3 more sources

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